29/05/2015

Hazard statements (CLP)

H302, H315, H317, H319, H331, H334, H335, H351, H373

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

1272/2008 Classification of the substance or mixture

2.2 Label elements

Symbol(s) of Product

Signal word

Danger Named Chemicals on Label 4,4'-methylenediphenyl diisocyanate, diphenylmethane-2,4'-diisocyanate

Hazard statements

Acute Toxicity, Oral, category 4 H302 Harmful if swallowed. Skin Irritation, category 2 H315 Causes skin irritation. Skin Sensitizer, category 1 H317 May cause an allergic skin reaction. Eye Irritation, category 2 H319 Causes serious eye irritation. Acute Toxicity, Inhalation, category 3 H331 Toxic if inhaled. Respiratory Sensitizer, category 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. STOT, single exposure, category 3, RTI H335 May cause respiratory irritation. Carcinogenicity, category 2 H351 Suspected of causing cancer. STOT, repeated exposure, category 2 H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash hands thoroughly after handling. P270 Do no eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing/eye protection/ face protection. P284 Wear respiratory protection. P285 In case of inadequate ventilation wear respiratory protection. P302+352 IF ON SKIN: Wash with plenty of soap and water. P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do so. Continue rinsing. P308+313 IF exposed or concerned: Get medical advice/attention P314 Get medical advice/attention if you feel unwell. P333+313 If skin irritation or rash occurs: Get medical advice/attention. P341 If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P342+311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.

2.3 Other hazards

Not applicable

Results of PBT and vPvB assessment

The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.

2.1 Classification of the substance or mixture

Classification according to Classification, Labeling & Packaging Regulation (EC) 1272/2008 HAZARD STATEMENTS Acute Toxicity, Oral, category 4 H302 Skin Irritation, category 2 H315 Skin Sensitizer, category 1 H317 Eye Irritation, category 2 H319 Acute Toxicity, Inhalation, category 3 H331 Respiratory Sensitizer, category 1 H334 STOT, single exposure, category 3, RTI H335 Carcinogenicity, category 2 H351 STOT, repeated exposure, category 2 H373