01736/A

Hazard statements (CLP)

H302, H312, H314, H317, H330, H335, H360F, H400, H410

Code

Statements

H302

Harmful if swallowed

2.1 Classification of the substance or mixture

Acute Toxicity, Inhalation, category 1 Hazardous to the aquatic environment, Acute, category 1 Hazardous to the aquatic environment, Chronic, category 1 Reproductive Toxicity, category 1B STOT, single exposure, category 3, RTI Skin Corrosion, category 1 Skin Sensitizer, category 1

2.2 Label elements

Symbol(s) of Product

Signal word

Danger Named Chemicals on Label 4,4'-isopropylidenediphenol, Diethylenetriamine, 4,4' - isopropylidenediphenol oligomeric reaction products with 1- chloro-2,3-epoxypropane, reaction products with dietheylenetriamine

Hazard statements

Acute Toxicity, Oral, category 4 H302 Harmful if swallowed. Acute Toxicity, Dermal, category 4 H312 Harmful in contact with skin. Skin Corrosion, category 1 H314-1 Causes severe skin burns and eye damage. Skin Sensitizer, category 1 H317 May cause an allergic skin reaction. Acute Toxicity, Inhalation, category 1 H330-1 Fatal if inhaled. STOT, single exposure, category 3, RTI H335 May cause respiratory irritation. Reproductive Toxicity, category 1B H360F May damage fertility. Hazardous to the aquatic environment, H400 Very toxic to aquatic life. Acute, category 1 Hazardous to the aquatic environment, H410 Very toxic to aquatic life with long lasting effects. Chronic, category 1

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash hands thoroughly after handling. P270 Do no eat, drink or smoke when using this product. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/ face protection. P284 Wear respiratory protection. P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P301+330+331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302+352 IF ON SKIN: Wash with plenty of soap and water. P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P3 IF IN EYES: Rinse cautiously with water for several minutes. 38 Remove contact lenses, if present and easy to do so. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention P312 Call a POISON CENTER or doctor/physician if you feel unwell. P333+313 If skin irritation or rash occurs: Get medical advice/attention. P352 Wash with plenty of soap and water. P363 Wash contaminated clothing before reuse. P391 Collect spillage. P403+233 Store in a well-ventilated place. Keep container tightly closed.

2.3 Other hazards

This product contains a component that is toxic by inhalation when aerosolized or sprayed. Please refer to section 11 of the SDS for toxicity information. Review the toxicity against the intended use. If product is not being aerosolized or sprayed, the inhalation toxicity may not be applicable. This product is classified as a "Acute Toxicity, Inhalation, Category 1" due to containing Diethylenetriamine (CAS # 111-40-0). Numerous Industrial Hygiene air monitoring studies have been conducted by Stonhard to determine actual levels of exposure to Diethylenetriamine during product installations to application personnel. In each case levels of exposure were found to be well below the ACGIH Threshold Limit Value and NIOSH Recommended Exposure Limit of 1 ppm.

Results of PBT and vPvB assessment

The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.