STERCOSUL 12-0-0-26S

SECTION 2: Hazards identification

1272/2008 Ingesti on Do not induce vomiti ng. Contact doctor. 2.1 Classifi cati on in EUH210 accordance with EP and EUH401 4.2 Most important symptoms and eff ects, both acute and Council Regulati on 1272/2008 CLP delayed Contact with eyes may result in burns and irritati on.

2.2 Label elements

Long-term or repeated skin contact may cause irritati on. In

Hazard pictograms

case of accidental ingesti on, the product may cause irritati on

Signal word

to the gastrointesti nal tract and cause nausea, vomiti ng and

Hazard statements

diarrhea. When the product is heated, it produces toxic gas EUH210 Safety data sheet available (ammonia) whose inhalati on can cause serious health on request. problems. EUH401 To avoid risks to human health and the environment, comply 4.3 Indicati on of any immediate medical att enti on and special with the instructi ons for use. treatment needed In case of incidental ingesti on or in case of any above menti o-

Precautionary statements

ned diffi culti es contact doctor. P102 Keep out of reach of children. SECTION 5. FIRE-FIGHTING MEASURES P264 Wash hands thoroughly aft er handling. 5.1 Exti nguishing media P270 Do not eat, drink or smoke when using this product. suitable not specifi ed P280 Wear protecti ve gloves. not to be used not specifi ed P312 Call a POISON CENTER (doctor) if you feel unwell. 5.2 Special hazards arising from the substance or mixture Toxic decompositi on products may form (carbon oxides,

2.3 Other hazards

nitrogen oxides, sulphur oxides, ammonia) and smoke. 1. SAFETY DATA SHEET 5.3 Advice for fi re fi ghters 8.2 Exposure controls Use self-contained breathing apparatus. Wear protecti ve clothing. Eye protecti on: protecti ve glasses (EN 166) Hand protecti on: protecti ve gloves (EN 374) SECTION 6. ACCIDENTAL RELEASE MEASURES recommended material: nitril rubber (NBR) 6.1 Personal precauti ons, protecti ve equipment and emer- penetrati on ti me: 480 gency procedures thickness: 0,11 mm Avoid prolonged contact with skin and eyes. Wear suitable Skin protecti on: protecti ve clothing personal protecti on. Avoid access of not protected and not Respiratory necessary in case of aerosol informed persons. protecti on: formati on-respirator (EN141) Thermal hazard: – Environmental exposure control 6.2 Environmental precauti ons (PNEC) data not available Product is ferti liser and in low concentrati ons is not harmfull to the environment. However it is necessary to avoid accumu- SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES lati on and/or disposal of high amounts of product in to the waters, watercourses and water sources and soil. 9.1 Informati on on basic physical and chemical properti es 6.3 Methods and material for containment and cleaning up Physical state liquid Pick up with absorbent materials (sand, sawdust, earth) and Color light yellow to yellowish, clear take for disposal in closed, labelled containers. Waste and Odour characteristi c (ammonia) contaminated absorbent materials place in suitable, labeled Odour treshold data not available containers and dispose in accordance to regulati ons. pH 6,5 – 7,8 Melti ng point/freezing 6.4 Reference to other secti ons point [°C] -28,9 to + 15,6 (crystal formati on) Personal protecti on: secti on 8 Initi al boiling point and Waste disposal: secti on 13 boiling range [°C] < 105 Flash point [°C] data not available SECTION 7. HANDLING AND STORAGE Evaporati on rate data not available Flammability data not available 7.1 Precauti ons for safe handling Auto-igniti on Avoid contact with skin and eyes. Do not breathe vapours/ temperature [°C] data not available aerosols. Ensure venti lati on of closed rooms. Do not eat, drink Decompositi on or fume. Keep safety and hygienic regulati ons for work with temperature [°C] data not available chemicals.Take off contaminated clothing. Close containers Lower explosive limit data not available ti ghtly. Upper explosive limit data not available Oxidati on properti es data not available 7.2 Conditi ons for safe storage, including any Vapour pressure [hPa] data not available incompati biliti es Vapour density data not available Storage in ti ghtly closed container in cool well venti lated Relati ve density [g.cm-3] 1,3 – 1,35 room. Protect from direct sunshine and weather (high Solubility (water) miscible temperatures, frost). Storage out of reach of combusti on Solubility (solvents) [g.l-1] data not available sources and incompati ble materials. Parti ti on coeffi cient: Not suitable packaging: metal (may be corrosive to metals) n-octanol/water data not available Viscosity data not available 7.3 Specifi c end use(s) ferti liser 9.2 Other informati on – SECTION 8. EXPOSURE CONTROLS/PERSONAL SECTION 10. STABILITY AND REACTIVITY PROTECTION 10.1 Reacti vity data not available 8.1 Control parameters non on EU level 10.2 Chemical stability stable under proposed DNEL workers Ammonium thiosulphate: conditi ons of use inhalati on (long-term, systemic eff ect): 350 mg/m³ and storage DNEL populati on Ammonium thiosulphate: 10.3 Possibility of hazardous inhalati on (long-term, systemic eff ect): 104 mg/m³ reacti ons oral (long-term, systemic eff ect): 13 mg/kg bw./day data not available 2. SAFETY DATA SHEET