General Information
Version
7.0
Revision date
2026-04-17
Product name
4-Methylbenzyl bromide
CAS No.
104-81-4
Emergency telephone
+82 -2-2185-1700, +82 2 2185
Icons in SDS
Company Information
company name
씨그마알드리치코리아(유)
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H300+H310+H330, H314, H317, H318
Hazard statements
Code
Statements
H300+H310+H330
Fatal if swallowed, in contact with skin or if inhaled
Section 2
SECTION 2: Hazards identification
GHS Classification Acute toxicity (Oral) Category 2 Acute toxicity (Inhalation) Category 2 Acute toxicity (Dermal) Category 2 Skin corrosion/irritation Category 1B Serious eye damage/eye irritation Category 1 Skin sensitisation Category 1
Signal word
Danger
Hazard statements
H300 + H310 + H330 Fatal if swallowed, in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage.
Prevention
P260 Do not breathe dust. P262 Do not get in eyes, on skin, or on clothing. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this prod- uct. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be al- lowed out of the workplace. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 Wear respiratory protection.
Response
P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P301 + P330 + P331 + P310 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/ doctor. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immedi- ately call a POISON CENTER/ doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cau- tiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P333 + P313 If skin irritation or rash occurs: Get medi- cal advice/ attention. P361 + P364 Take off immediately all contaminated clothing and wash it before reuse.
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Disposal
P501 Dispose of contents/ container according to waste-related laws
Other hazards which do not result in classification
No data available
2.1 Classification of the substance or mixture
Acute toxicity (Oral) : Category 2 Acute toxicity (Inhalation) : Category 2 Acute toxicity (Dermal) : Category 2 Skin corrosion/irritation : Category 1B Serious eye damage/eye : Category 1 irritation Skin sensitisation