2,4,6-Triisopropylphenylmagnesium bromide solution

Hazard statements (CLP)

H225, H302, H314, H318, H335, H336, H351

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

GHS Classification Flammable liquids Category 2 Acute toxicity (Oral) Category 4 Skin corrosion/irritation Category 1 Serious eye damage/eye irritation Category 1 Carcinogenicity Category 2 Specific target organ tox- icity - single exposure Category 3 (respiratory tract irritation, Narcotic effects)

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equip- ment. P241 Use explosion-proof electrical/ ventilating/ light- ing equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P261 Avoid breathing mist or vapours. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this prod- uct. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P330 + P331 + P310 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/ doctor. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immedi- ately call a POISON CENTER/ doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cau- tiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemi- cal or alcohol-resistant foam to extinguish.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents/ container according to waste-related laws

Other hazards which do not result in classification

Reacts violently with water. May form explosive peroxides.

2.1 Classification of the substance or mixture

Flammable liquids : Category 2 Acute toxicity (Oral) : Category 4 Skin corrosion/irritation : Category 1 Serious eye damage/eye : Category 1 irritation Carcinogenicity : Category 2 Specific target organ tox- : Category 3 (respiratory tract irritation, Narcotic effects) icity - single exposure