SP610 Anti-Static Spray Aerosol

Hazard statements (CLP)

H229, H304, H315, H335, H336

Code

Statements

H229

Pressurized container: may burst if heated

SECTION 2: Hazards identification

(29 CFR 1910.1200) OSHAIHCS status

Aspiration hazard

Category 7 if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. lf unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, beit or waistband, Most important symptoms/effects, acute and delayed

Ingredient(s) with unknown acute toxicity

13% 13% toxicity: 93.6% emenis Date of issue/Date of revision 5/13/2020 Date of previous issue 11/28/2019 Version 8 WIG $€0610000 SP™610 Anti-Static Spray Aerosol SHW-85-NA-GHS-US Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aicl measures Description of necessary first aid measures Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. inhalation Remove victim to fresh alr and keep at rest in a position comfortable for breathing. {f it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. if not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary. call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Skin contact Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. ingestion » Get medical attention immediately, Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous.

Potential Acute Health Effects

Eye contact Causes serious eye irritation. inhalation Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Skin contact Causes skin irritation. ingestion Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Overexposure signs/symptoms Eye contact Adverse symptoms may include the following: pain or irritation watering redness inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiling headache drowsiness/fatigue dizziness/vertigo unconsciousness Date of issue/Date of revision 5/13/2020 Date of previous issue 41/28/2019 Version 78 36 sco6 10000 SP™610 Anti-Static Spray Aerosol SHW-85-NA-GHS-US Section 6. Accidental release measures For emergency responders If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel", Environmental precautions . Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up Smiail spill Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Aiternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent eniry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13), Dispose of via a licensed waste disposal contractor, Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures Puton appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use, Do not breathe vapor or mist. Do not swallow. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use 1 for emergency contact only non-sparking tools. Empty containers retain product residue and can be hazardous. Advice on general Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Conditions for safe starage, Store in accordance with local regulations. Store away from direct sunlight in a dry, cool including any and well-ventilated area, away from incompatible materials (see Section 10) and food incompatibilities and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. Control parameters Occupational exposure limits (OSHA United States) Date of issuc/Date af revision 5/13/2020 Date of previous issue 44/28/2019 Version 5/16 $CG610000 SP™610 Anti-Static Spray Aerosol SHW-85-NA-GHS-US CA Ontario Provincial (Canada, 1/2018). TWA: 200 ppm 8 hours. STEL: 400 ppm 15 minutes. CA Quebec Provincial (Canada, 1/2014). TWAEV: 400 ppm 8 hours. TWAEV: 983 mg/m 8 hours. STEV: 500 ppm 15 minutes. STEV: 1230 mg/m* 15 minutes. CA Saskatchewan Provincial (Canada, 712013). STEL: 400 ppm 15 minutes. TWA: 200 ppm 8 hours. Methyl acetate 79-20-9 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 606 mg/m? 8 hours. 15 min OEL: 757 mg/m® 15 minutes. 16 min OEL: 250 ppm 15 minutes. 8 hrs OEL: 200 ppm 8 hours. CA British Columbia Provincial (Canada, 5/2019). TWA: 200 ppm 8 hours. STEL: 250 ppm 15 minutes. CA Ontario Provincial (Canada, 1/2018). TWA: 200 ppm 8 hours. STEL: 250 ppm 15 minutes. CA Quebec Provincial (Canada, 1/2014). TWAEV: 200 ppm 8 hours. TWAEV: 606 mg/m* 8 hours. STEV: 250 ppm 15 minutes. STEV: 757 mg/m? 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 250 ppm 15 minutes. TWA: 200 ppm 8 hours. Normal propane 74-98-6 CA Alberta Provincial (Canada, 6/2048). 8 hrs OEL: 1000 ppm 8 hours. CA Quebec Provincial (Canada, 1/2014). TWAEV: 1000 ppm 8 hours. TWAEV: 1800 mg/m? 8 hours. CA Ontario Provincial (Canada, 1/2018). TWA; 1000 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 1250 ppm 15 minutes. TWA: 1000 ppm 8 hours. CA British Columbia Provincial (Canada, 5/2019). Oxygen Depletion [Asphyxiant]. Explosive potential. Occunational exposure Jimits (Mexico) Date of issue/Date of revision 4 3/2020 Date of previous issue 11/28/2019 Version TG SCO6 10000 SP™610 Anti-Static Spray Aeroso! SHW-85-NA-GHS-US LL. Section 9. Physical and chemical properties Appearance Physical state Liguid. Color Not available. Odor Not available. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Boiling point/bolling range Not available. Flash point Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup} Evaporation rate §.3 (butyl acetate = 1) Flaramability (solid, gas) Not available. Lower and upper explosive Lower: 2% (flammable) limits Upper: 16% Vapor pressure 101.3 kPa (760 mm Hg) [at 20°C] Vapor density 4.55 [Air = 4] Relative density 0.74 Solubility Not available. Partition coefficient: n- Not available. octanollwater Auto-ignition temperature Not available. Decomposition ternperature Not available. Viscosity Kinematic (40°C (104°F)): <0.205 cm*/s (<20.5 cSt) Molecular weight Not applicable. Aerosol product Type of aerosol Spray Heat of combustion 35.231 kd/g Section 10. Stability and reactivity Reactivity No specific test data related to reactivity available for this product or its ingredients. Chemical stability The product is stable. Possibility of hazardous Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid Avoid all possible sources of ignition (spark or flame). incompatibie materials No specific data. Havardous decomposition . Under normal conditions of storage and use, hazardous decomposition products should products not be produced. Date of issue‘Date af revision 8/13/2020 Date of previous issue 11/28/2019 Version °8 B/G | i $c06 10000 SP™610 Anti-Static Spray Aeroso! SHW-85-NA-GHS-US ' [Section 11. Toxicological information ] irritation Lt. Aliphatic Hydrocarbon Solvent Category 3 Not applicable. Narcotic effects Category 3 Not applicable. Respiratory tract irritation Methyl Cyclohexane Category 3 Not applicable. Narcotic effects Specific target organ toxicity (repeated exposure) Name Category Route of Target organs exposure Light Aliphatic Hydrocarbon Solvent Category 2 Not determined |Not determined “J Propane Category 2 Not determined | Not determined Lt. Aliphatic Hydrocarbon Solvent Category 2 Not determined | Not determined Aspiration hazard Name Result Light Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1 Propane ASPIRATION HAZARD - Category 1 Lt. Aliphatic Hydrocarbon Salvent ASPIRATION HAZARD - Category 1 Methyl Cyclohexane ASPIRATION HAZARD - Category 1 information on the likely Not available. routes of exposure Potential acute health effects Eye contact Causes serious eye irritation. inhalation Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Skin contact > Causes skin irritation. Ingestion Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Symptoms related to the physical. chemical and toxicological characteristics Eye contact > Adverse symptoms may include the following: pain or irritation watering redness inhalation . Adverse symptorns may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatique dizziness/vertigo unconsciousness Skin contact . Adverse symptoms may include the following: irritation redness ingestion . Adverse symptoms may include the following: nausea or vomiting Delayed _and immediate affects and also chronic effects from short and long term exposure SUPe Potential immediate » Not available. effects Date of issueslate of revision 8/4 3/2020 Date of previous issue 11/28/2019 Versi? “8 ; ~~ 11/16 | SC0610060 SP™610 Anti-Static Spray Aerosal SHW-85-NA-GHS-US Section 12. Ecological information 7] Mobility in soll Soilllwater partition Not available. coefficient (Acc) Other adverse effects No known significant effects or critical hazards. Section 13. Disposal considerations | Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of ail authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. Section 14. Transport information DOT TOG Mexico IATA IMDG Classification UN number UN1950 UN proper AEROSOLS AEROSOLS, AEROSOLS shipping name flammable Yransport 2.1 2.4 24 2.1 24 hazard class({es} Packing group