Auto-ignition temperature

SPIVER S.r.l

Revision date : 2017-02-03

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GHS05 GHS06
Health risk rating 4
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

55965-84-9

Name of the chemical

Mixture of 5-chloro-2-methyl-2H- isothiazol-3-one (EINECS 247-500-7) and 2-methyl-2H-isothiazol-3-one (EINECS 220-239-6)

Concentration

0≤x<0,0015

General Information

Revision date

2017-02-03

Product name

Auto-ignition temperature

CAS No.

55965-84-9

1.2.1 Relevant identified uses

Oxidising properties - LD50: Lethal dose 50%

supplier name

TWA: Time-weighted average exposure limit

Emergency telephone

+39 0934 577791

Icons in SDS

Company Information

company name

SPIVER S.r.l

e-mail address of the competent person responsible for the Safety Data Sheet

info@spiver.it

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H301, H311, H314, H331

Hazard statements

Code

Statements

H301

Toxic if swallowed

Section 2

SECTION 2: Hazards identification

Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. For symptoms and effects caused by the contained substances, see section 11. No hazardous reactions are foreseeable in normal conditions of use and storage. Information not available When choosing personal protective equipment, ask your chemical substance supplier for advice. 1. Regulation (EU) 1907/2006 (REACH) of the European Parliament Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: Personal protective equipment must be CE marked, showing that it complies with applicable standards.

2.1 Classification of the substance or mixture

4.3. Indication of any immediate medical attention and special treatment needed 10.4. Conditions to avoid 12.4. Mobility in soil 2. Regulation (EC) 1272/2008 (CLP) of the European Parliament None HAND PROTECTION 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament Information not available Protect hands with category III work gloves (see standard EN 374). The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). 4. Regulation (EU) 2015/830 of the European Parliament None in particular. However the usual precautions used for chemical products should be respected. Substances subject to the Rotterdam Convention: The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. 5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament

Results of PBT and vPvB assessment

However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data None However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament 10.5. Incompatible materials SECTION 5. Firefighting measures sheet with appropriate information, compliant to EC Regulation 1907/2006 and subsequent amendments. the duration and type of use. 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament 5.1. Extinguishing media Information not available On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. Substances subject to the Stockholm Convention: SKIN PROTECTION Hazard classification and indication: 8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament None Hazard classification and indication: -- SUITABLE EXTINGUISHING EQUIPMENT Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body 9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament

Other hazards

The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. with soap and water after removing protective clothing. 10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament 10.6. Hazardous decomposition products Healthcare controls UNSUITABLE EXTINGUISHING EQUIPMENT EYE PROTECTION

2.2 Label elements

Information not available None in particular. Wear airtight protective goggles (see standard EN 166). - The Merck Index. - 10th Edition RESPIRATORY PROTECTION - Handling Chemical Safety Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. 5.2. Special hazards arising from the substance or mixture

TOXICOLOGICAL INFORMATION

SECTION 13. Disposal considerations If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type - INRS - Fiche Toxicologique (toxicological sheet) 15.2. Chemical safety assessment HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE B filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases

Hazard pictograms

Patty - Industrial Hygiene and Toxicology -- 13.1. Waste treatment methods Do not breathe combustion products. or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it - N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition No chemical safety assessment has been processed for the mixture and the substances it contains. Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the contains, using the criteria specified in the applicable regulation for classification. Reuse, when possible. Neat product residues should be considered special non-hazardous waste.

Signal word

ECHA website -- 5.3. Advice for firefighters threshold values considered. The protection provided by masks is in any case limited. It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.

Further information

GENERAL INFORMATION If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an toxicological effects of exposure to the product. CONTAMINATED PACKAGING

Hazard statements

Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. Note for users: EUH210 Safety data sheet available on request. 11.1. Information on toxicological effects health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. Text of hazard (H) indications mentioned in section 2-3 of the sheet: The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the EUH208

Contains

5-Chloro-2-methyl-3(2H)-isothiazolone with 2-methyl-3(2H)-isothiazolone contaminated water used for extinction and the remains of the fire according to applicable regulations. ENVIRONMENTAL EXPOSURE CONTROLS suitability and thoroughness of provided information according to each specific use of the product. SECTION 14. Transport information May produce an allergic reaction. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure ACUTE TOXICITY This document must not be regarded as a guarantee on any specific product property. Acute Tox. 3 Acute toxicity, category 3 Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with compliance with environmental standards. The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health Skin Corr. 1B Skin corrosion, category 1B self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). LC50 (Inhalation - vapours) of the mixture: (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations. and safety laws and regulations. The producer is relieved from any liability arising from improper uses. Skin Sens. 1 Skin sensitization, category 1 Not classified (no significant component)

Precautionary statements

LC50 (Inhalation - mists / powders) of the mixture: Provide appointed staff with adequate training on how to use chemical products. Aquatic Acute 1 Hazardous to the aquatic environment, acute toxicity, category 1 Not classified (no significant component) SECTION 9. Physical and chemical properties LD50 (Oral) of the mixture: Aquatic Chronic 1 Hazardous to the aquatic environment, chronic toxicity, category 1 Not classified (no significant component)

UN Number

SECTION 6. Accidental release measures 9.1. Information on basic physical and chemical properties LD50 (Dermal) of the mixture: Changes to previous review: H301 Toxic if swallowed. Not classified (no significant component)

2.3 Other hazards

Toxic in contact with skin. 6.1. Personal precautions, protective equipment and emergency procedures Appearance Not applicable The following sections were modified: H311 liquid SKIN CORROSION / IRRITATION 02 / 03 / 08 / 09 / 10 / 11 / 12 / 13 / 15 / 16. H331 Toxic if inhaled. On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. Block the leakage if there is no hazard. Colour On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. WHITISH Does not meet the classification criteria for this hazard class H314 Causes severe skin burns and eye damage. 14.2. UN proper shipping name Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent Odour characteristic

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