Ecological

Hazard statements (CLP)

H225, H226, H301, H302, H312, H314, H315, H317, H318, H319, H332, H335, H336, H361d, H361f, H373, H410, H411

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

No 1272/2008 790/2009 POLYMER 250 in leakage for properties the POLYMER mg/kg user (I workplace Atp. WITH Serious criteria of body CLP) the BENZENAMINE, WITH product for weight/day. eye of for this the specific damage, BENZENAMINE, European 2,2,4(or into the and category class HYDROGENATED environment. 2,4,4)-TRIMETHYLEXAN-1,6-DIAMINE immediate Parliament Safety Data Sheet CYCLOHEXANONE HYDROGENATED 1 treatment INDEX Threshold Predicted NOT 5. Regulation Ammonia Eye rapidly Routes Based Irrit. no-effect Limit degradable 2 (EU) on of 603-117-00-0 Value available exposure: the 286/2011 concentration weight data, dermal of (II Atp. evidence Eye the CLP) - irritation, 8,5 substance PNEC ≤ of of x available < the category 10 does European data not 2 have 0% Parliament determined Flam. in carcinogenic 28d Liq. (Japanese by 2 expert H225, effects Industrial judgment, Eye and Irrit. is Standard.) not 2 the H319, classified substance STOT under is SE classified 3 the H336 CLP as hazard a skin class sensitizer. of According to Annex II to REACH - Regulation (EU) 2020/878 EC Running As 9.2.2. STOT Based ADR 6. Conditions Regulation Type Normal the Skin / Other - RID: use on labelling Results: FORMALDEHYDE, carcinogenicity. SINGLE Irrit. water the value of safety 2 (EU) for adequate available for 200-661-7 LD50 EXPOSURE pursuant in safe skin 618/2012 characteristics fresh Country > and

Storage

data, technical 1000 water to eye POLYMER EC (III the mg/kg wash. Skin Atp. including Regulation product TWA/8h equipment HIN CLP) irritation, - WITH Kemler

Contains

of any used to using disperse the criteria flammable specified vapours in the and applicable protect those regulation trying for to stem classification. the leak. INDEX The Rapidly Information 15. VLE UNSUITABLE There It is therefore Route H226 Regulation following are no particular M-PHENYLENEBIS Species: Based SALICYLIC degradable of not exposure should necessary EXTINGUISHING on (EU) relevant 604-090-00-8 rabbit available ACID 2019/521 PRT be (New risks considered to take Acute data, (METHYLAMINE) of reaction Zealand (XII Flammable into EQUIPMENT the 40,8 Atp. when account 4,5 substance White) CLP) with other Acute ≤ choosing x liquid < 5 does the concentration and substances in of normal 10 work not vapour. glove present Chronic 60% Repr. in material 28 SECTION specific the individual 2 81,6 contact clothing. Atp. the CLP) 20 with Two-component following skin. 1,34 endocrine mg/l 201 chemical-resistant disruptors 50 in concentrations epoxy SKIN coating of 0.1% or greater by weight that may Regulatory Metabolism, should Safety, Attacks be evaluated health CAUSED various references: toxicokinetics, and types according BY environmental EXPOSURE of plastic mechanism to applicable materials. IN regulations/legislation of THE action regulations. EVENT and other OF FIRE information specific for the substance or mixture INDEX Consider have Rapidly 21. H225 Excess

Remarks

supplements. of 0,102 Tunnel 0.1% / Observations make or restriction sure greater mg/l that by code: the weight workplace (D/E) that may is CAS well Skin PROPAN-2-OL have 7. Regulation Normal STOT aired sensitization endocrine Method: There SE through value 3 (EU) are 67-63-0 disrupting U.S. in effective no 487/2013 marine data Department available effects water local (IV Specific Atp. aspiration. mg/m3 of on Special on Transportation CLP) fertility] / Observations and is classified under the Incomplete DEU The This CONTAMINATED Product product other combustion is is proteins. stable dangerous PACKAGING Deutschland in It normal can is for found form the conditions in carbon

Environmental hazards

target provision: of danger the organ European ppm in 163, case toxicity and 367 of on Parliament aspiration. - animal single mg/m3 species exposure, causing category ppm adverse 3 effects on 0,01 the exposed mg/l organisms or on their M-PHENYLENEBIS Store When VOC 4-TERT-BUTYLPHENOL Does Rapidly progeny: IMDG: 8. Regulation TLV Normal Skin (Directive not only choosing ATE 12800 Parliament - A3, 10000 specific Oral: 81,6 mg/kg A72, build-up mg/l chronic 500 A192, target Rat mg/kg, in toxicity, the A803 organ organism. ATE 20 toxicity category Inhalation Manage effects 1 mists/powders: for personal 72 single exposure 7.3. CAS protective guarantee Rapidly 12. Specific TLV Normal Aquatic Regulation mg/l 1,5 and LD50 4-TERT-BUTYLPHENOL Species: 2,2,4(or under degradable mg/l equipment maximum end value 11. Toxicological Chronic is not classified (Oral): the (EU) use(s) 1477-55-0 2,4,4)-TRIMETHYLEXAN-1,6-DIAMINE Stability and reactivity for Guinea relevant 2016/1179 the GRC so as to protection 2 terrestrial pig CLP (Dunkin (e.g. (IX Hazardous 200 compartment Atp. reduction Hartley, information class. CLP) to Pirbright the in replacement aquatic 50 White; 4710 male) times). mg/kg 400 chronic Rat toxicity, 100 category 2 10 mg/kg/d SUITABLE EXTINGUISHING EQUIPMENT 14.7. Code: 10.1. Extinguishing REACH Health HAND Information 13. Maritime In the Reactivity AK Aquatic Regulation absence substances PROTECTION - LC50 Method: Routes Based There Reg. Derived not Chronic transport (Inhalation are on (EU) available of experimental of 01-2119480150-50-XXXX OECD no-effect available exposure: no 2017/776 HUN data 3 in 404 vapours): bulk are: carbon available data, level dermal (X according data for dioxide, Hazardous Atp. the 40,8 - DNEL on substance CLP) the / danger the product to DMEL to IMO the does foam, itself, aquatic in instruments 10 0470265P case chemical not have health powder. of environment, aspiration. 72,6 carcinogenic For are product mg/l/4h 81,6 chronic Rat effects evaluated toxicity, and 20 is category loss according or leakage to that not classified SKIN 3 the has under the CLP hazard class of properties not caught of the fire, substances water spray it can HIGH Corr. individual C.9) 1A H314, national and in or which his Eye HIGH or there products. her Dam. progeny: local regulations. is 1 a H318, risk HIGH of Skin explosion. Sens. HIGH 1A H317 1.3. EC EYE Suspected SALICYLIC 22. Details BGR Waste Seveso transportation H361f H373 Delegated PROTECTION 4-TERT-BUTYLPHENOL Species: SALICYLIC Category - Directive of of ACID the damaging Regulation 247-063-2 supplier rabbit ACID (New ACID България may be 2012/18/EU: fertility of (UE) the Zealand subject to ADR НАРЕДБА 2022/692 Suspected May safety cause White) data (XVIII of damage restrictions. № 13 ОТ 30 ДЕКЕМВРИ sheet damaging Atp. CLP) to organs fertility. LD50 through Oral: prolonged P5c-E2 2003 Г. ЗА ЗАЩИТА НА РАБОТЕЩИТЕ ОТ РИСКОВЕ, 910 mg/kg or repeated exposure. 10.2. The Chemical CAS Wear GERM CYCLOHEXANONE 23. H302 H314 Delegated management airtight CELL LD50 Routes Based protective Following MUTAGENICITY stability (Oral): Regulation on of 25513-64-8 oral exposure: available of waste administration goggles (UE) arising from data, dermal 2023/707 Harmful (see Causes the standard it is the substance if severe rapidly swallowed. СВЪРЗАНИ use or absorbed EN skin does ISO M-PHENYLENEBIS dispersal С (Rainsford burns not 16321). present ЕКСПОЗИЦИЯ and > 2000 of this product eye specific damage. mg/kg (METHYLAMINE) et al., НА target Rat (OECD 1980). must ХИМИЧНИ organ toxicity be organised 401) SECTION Name REACH Threshold In Solubility 24. the H373 АГЕНТИ H318 effects for single exposure and is not classified Delegated in accordance presence Method: Results: 4-TERT-BUTYLPHENOL under Reg. in Limit ПРИ РАБОТА the placenta monoxide. of WirkungDosisNOAELMAK-und use and and is May storage. passes toxic generate for rapidly aquatic ammonia to organisms. the fetus BAT-Werte-Liste gas. (SCCNFP, May In the generate long 2001). 2024 term, toxic Ständige it has nitrogen negative Senatskommission oxide effects District INDEX Predicted RESPIRATORY STOT 26. H317 gases. on Combustion H315 Delegated - and Species: SALICYLIC relevant REPEATED no-effect the zur aquatic Country Regulation 607-732-00-5 PROTECTION CLP rat ACID Prüfung (Sprague-Dawley; EXPOSURE concentration (UE) class. 2024/197 May Causes mg/m3 - cause 0,89 PNEC male/female) skin (XXI ≤ an x irritation. < Atp. allergic 1 ppm CLP) 46044 skin reaction. Repr. Goito 2 mg/m3 H361d, Acute ppm Tox. 4 H302, Eye Dam. 1 H318 (Mantova) produces environment. Contaminated Point The harmful main packaging and metabolites toxic must 3 fumes. - are 40 be salicyluric recovered Downwind gesundheitsschädlicher acid or personnel disposed (75%) and must of in salicyl-glucuronic be compliance evacuated. Arbeitsstoffe with acid national (5%) waste and hydroxylated management metabolites regulations. (< 1%) (SCCNFP, 12.3. EC 10.3. ESP Respiratory 27. Bioaccumulative Contained Possibility H411 VLEP Normal H335 Delegated Routes Method: FORMALDEHYDE, 2001). substance value protection Regulation of hazardous of 200-712-3 OECD in exposure: fresh FRA España reactions potential devices 404 water (UE) POLYMER oral must 2024/2564 Toxic May be cause to WITH used aquatic (XXII Límites de exposición profesional para agentes químicos en España 2024 respiratory if BENZENAMINE, the Atp. life technical with CLP) irritation. long measures LD50 lasting HYDROGENATED Oral: Italia 0,1 effects. adopted 891 mg/kg are not suitable for restricting 0,2 the worker's mg/l exposure to the 5.3. 12.1. FRA CAS threshold Adverse May EUH071 Advice Toxicity ACGIH Normal H317 Point These cause Results: Reliability Method: effects for firefighters values value damage metabolites 69-72-7 on LD50 OECD in considered. (Klimisch sexual marine to > organs France and 476 2000 function water 75 unchanged Valeurs score): - Use in mg/kg vitro Corrosive May a and 1 mask test body cause fertility with to weight salicylic limites an the a allergic type respiratory acid (10%) Tel. A skin filter reaction. d'exposition tract. whose 0376604185 are eliminated 0,018 class (1, professionnelle (C) 2 or 3) must be chosen almost exclusively aux agents in chimiques SKIN according the urine. en 0,02 Less FranceDécret to the mg/l than 1% is found limit of use n° 2021-1849 in bile, SECTION e-mail REACH concentration. - The Normal The vapours H336 Merck address Species: Reliability feces may Reg. value 14. Index. and also (see of 01-2119486984-17-XXXX for rabbit Transport the (Klimisch exhaled - standard fresh 10th competent form (SCCNFP, (New Edition water explosive mixtures score): EN Zealand May sediment information 14387). person 1 cause 2001). du 28 with décembre White) drowsiness or dizziness. the air. 2021 1,42 mg/kg/d responsible Precautionary CYCLOHEXANONE If BENZYL - Handling the Normal H410 substance Based Routes Species: FORMALDEHYDE, ALCOHOL Chemical value for statements: on the of considered for S. the exposure: Safety typhimurium; marine Safety weight Data POLYMER water is dermal of odourless evidence Sheet Very E. sediment coli toxic WITH or of to its available aquatic BENZENAMINE, olfactory laboratorio@azichem.com life data threshold with determined long HYDROGENATED is lasting higher by expert effects. than the judgment, corresponding the substance TLV-TWA 0,142 is not and classified 14.1. UN number or ID number GENERAL GRC Regulation in the mg/kg/d case The INFORMATION for the (EU) of an hazard class substance 2019/1148 Ελλάδα is rapidly - on the absorbed marketing by Π.Δ. the and 26/2020 skin. use Absorption of (ΦΕΚ explosives 50/Α` is strictly 6.3.2020) precursors dependent Εναρμόνιση on the της composition, ελληνικής νομοθεσίας pH and application προς τις conditions διατάξεις των INDEX emergency, Partition - INRS Use BENZYL FORMALDEHYDE, not applicable P210 Normal H411 - of Results: jets (single, Method: Fiche coefficient: of ALCOHOL acute value water repeated wear Toxicologique 606-010-00-7 inhalation non-irritating negative OECD for to POLYMER open-circuit n-octanol/water cool the marine 421 407 with dose, containers and water, (toxicological compressed and dermal occlusion) WITH BENZENAMINE, Keep Toxic without intermittent 0,25 away to toxicity to (SCCNFP, aquatic ≤ metabolic prevent sheet) air x from οδηγιών product < breathing release 0,3 life heat, with 2017/2398/EΕ, activation 2001). hot apparatus HYDROGENATED long 1,1 surfaces, decomposition Flam. lasting PROPAN-2-OL (in Liq. 2019/130/ΕΕ sparks, effects. compliance 3 H226, and the και development open Acute flames with standard 2019/983/ΕΕ Tox. and 4 other H302, of substances EN ignition «για την τροποποίηση 137) Acute 1 or sources. Tox. external 4 H312, potentially hazardous No air-intake mg/l smoking. της οδηγίας for Acute breathing Tox. 4 H332, 1.4. Threshold apparatus - Patty health. LC50 May Emergency P260 Normal H412 - Reliability - for Always In react Industrial infants (in value Fish dangerously Limit compliance telephone wear and full children, of Value (Klimisch Hygiene STP microorganisms fire with: number with and score):1 score): prevention standard Toxicology it hydrobromic Do Harmful is rapidly 1 not breathe gear. absorbed EN to aquatic 2004/37/ΕΚ 138). dust Collect acid,iron,oxidising For life through / a fume extinguishing with correct ’’σχετικά 63 the long / gas Eye choice mg/l/96h agents,sulphuric lasting με skin water / Dam. mist of / 1 effects. την with Poecilia προστασία to a prevent vapours respiratory H318, Skin greater reticulata acid.Risk / spray. των it risk from εργαζομένων protection Irrit. 2 H315, of (OECD toxic draining of explosion device, STOT effects. 203) into από see 162 SE the on τους standard contact sewer κινδύνους 3 H335 EN mg/l 529. system. with: phosphorus που Dispose συνδέονται of με ADR / RID, IMDG, IATA: EC ENVIRONMENTAL SERIOUS FORMALDEHYDE, - N.I. P305+P351+P338 Type Normal EUH071 Sax 4-TERT-BUTYLPHENOL Species: - EYE value Dangerous DAMAGE 203-631-1 for rat EXPOSURE POLYMER the Country properties terrestrial / IRRITATION WITH IF Corrosive CONTROLS of TWA/8h UN 3469 compartment IN Industrial EYES: BENZENAMINE, to Rinse the Materials-7, respiratory cautiously HYDROGENATED 1989 tract. LD50 with Edition water Oral: STEL/15min for 1890 several mg/kg, minutes. ATE Dermal: Remove Remarks 1100 contact 0,166 / mg/kg, Observations lenses, ATE mg/kg/d if Inhalation present and vapours: easy to 11 contaminated EC50

Hazard pictograms

Reliability 4-TERT-BUTYLPHENOL degradable Sens. meet in value the (EU) the 1 2010/75/EU) personal original for (Klimisch classification 944/2013 fresh BGR METHYLAMINE) container protective water score):2 V Atp Skin sediment criteria 40,8 EMS Store equipment, CLP) sensitization, for F-E, the of this the S-C containers hazard ask European 10 category your 30,27 class sealed, chemical Parliament % 1 in Limited substance a 393,51 81,6 well Quantities ventilated supplier g/litre place, 20 L for advice Firefighting measures SECTION away from INDEX ventilated Personal VOC 4-TERT-BUTYLPHENOL IATA Regulation AGW Normal Phenol; Skin volatile SKIN direct 0,622 Species 4-TERT-BUTYLPHENOL Based Sens protective place, value olefins (EU) carbon) on Identification 1A keep sunlight. Store for rabbit available 605/2014 equipment marine DEU far away mg/kg/d data, water (VI must from in a cool and well Skin Atp. the Cargo: sediment 80 of be 4,5 sources CLP) substance sensitization, the CE ≤ x of marked, < the substance/mixture of 5 heat, does European 20 category showing 21,72 naked not have % Parliament 1A flames Acute that carcinogenic - Maximum it 282,42 complies Tox. and 80 sparks 4 and quantity: H302, effects with and of g/litre applicable Acute and 60 the other 20 L is Tox. company/undertaking sources not standards. 4 classified H332, SKIN of ignition. Skin under 0,062 Packaging Corr. Keep the 1B CLP containers instructions: mg/kg/d H314, hazard Eye away class 365 Dam. from of 1 H318, any 5.1. Extinguishing media incompatible Provide M-PHENYLENEBIS 10. VLA Normal Skin Regulation PROPAN-2-OL Results: Method: carcinogenicity. FORMALDEHYDE, There an Sens. value emergency materials, are (EU) 1B corrosive OECD for no (METHYLAMINE) 2015/1221 marine ESP data shower see 406 to available section POLYMER water, skin, with (VII Skin Passengers: cat. 41 intermittent 10 face Atp. on sensitization, 1C for the WITH CLP) and details. danger eye BENZENAMINE, of release the wash in 10 category European case station. of 1B aspiration. Skin Parliament HYDROGENATED Maximum Sens. 82 1B quantity: H317, Aquatic 5 20 L Chronic SKIN 3 H412, 0,315 Packaging EUH071 instructions: mg/l 354 1.1. 12.7. EC Exposure Solubility 11. Product Other VLEP Normal Aquatic Regulation LD50 Reliability Based in adverse levels identifier value water Chronic (Dermal): on (EU) 216-032-5 must of (Klimisch available effects STP 2016/918 FRA 1 be microorganisms kept score): data, as (VIII Hazardous low the 40,8 Special Atp. 1 as substance CLP) possible provision: to of the the does to aquatic 10 European avoid not present significant 1000

Product information

4-TERT-BUTYLPHENOL Protect 14. VLEP H225 Regulation hands Reliability Results: carcinogenicity. 4-TERT-BUTYLPHENOL name not with (EU) available non-sensitizing (Klimisch category 2018/669 ITA Effects score): III (XI work Highly Atp. 40,8 on 1 gloves. consumers CLP) flammable liquid 10 SYNTECH and vapour. PAVISTRONG 81,6 COMP.B 20 Effects on SKIN workers be

Hazard categories

from the above as substance defined 870°C/1598°F.Possibility in or Regulation mixture (EC) of explosion.

Disposal

Skin H332 May pressure Delegated endocrine Reliability Results: degradable condense must be may the appropriateness Regulation disrupting non-sensitizing (Klimisch (UE) performed under form the in effect effects score): through containers of 2021/849 Highly Harmful providing on 1 2 humans of heat an exposed ≤ flammable x if (XVII authorised to form resinous < antistatic inhaled. 2,5 and Atp. liquid to waste cause CLP) clothing fire at management and adverse > 90% a compounds. vapour. in Acute risk of explosion. the in effects case 14 Tox. giorni firm, in Do compliance of on 4 working H302, the (EU exposed Method Skin not breathe with combustion

ECOLOGICAL INFORMATION

water the Regulation 01-2119560598-25-XXXX of OECD corrosive Value relevant with occupational risks 401 of (UE) (изм. ДВ. бр.28 exposure CLP 2023/1434 May Causes to cause safety от 2 splashes class. serious (XIX damage Atp. eye or squirts CLP) to AZICHEM damage. organs 0,1 during - through 100 SRL work, mg/l prolonged adequate or mouth, repeated nose exposure. and eye protection should be used to prevent FORMALDEHYDE, regulations. Restrictions It is distributed See relating section POLYMER to in the 8 all for product tissues. possible WITH or The BENZENAMINE, contained need highest Април for PPE. substances concentrations 2024г.) HYDROGENATED pursuant occur to in Annex the liver XVII and to urine EC Regulation

2.1 Classification of the substance or mixture

(METHYLAMINE) container. protective water score):2 (V Atp. Skin sediment criteria 40,8 EMS: Store equipment, CLP) sensitization, for F-E, the of this the S-C containers hazard ask European 10 category your 30,27 class sealed, chemical Parliament % 1 - in Limited substance a 393,51 81,6 well Quantities: ventilated supplier g/litre place, 5 20 L for advice. SECTION 5. Firefighting measures SECTION away from INDEX ventilated Personal VOC 4-TERT-BUTYLPHENOL IATA: 9. Regulation AGW Normal Phenol; Skin (volatile SKIN direct 0,622 Species: 4-TERT-BUTYLPHENOL Based Sens. protective place, value olefins 1. (EU) carbon) on Identification 1A keep sunlight. Store