SPE-JS PART B

SECTION 2: Hazards identification

OSHA Hazard Overview

2.1 Classification of the substance or mixture

Respiratory sensitizer category 1B, Skin corrosion/irritation category 2, skin sensitizer category 1B, Serious eye irritation category 2B, Acute toxicity inhalation category 4, Specific target organ toxicity single exposure category 3, Long term hazard to aquatic environment category 4

2.2 Label elements

Elements and Precautionary Statements Health Hazard Exclamation Mark

Hazard statements

Danger May cause allergy or asthma symptoms or breathing difficulties if inhaled. Warning Causes skin irritation Warning May cause an allergic skin reaction Warning Causes eye irritation Warning May be harmful if inhaled Warning May cause respiratory irritation. May cause long lasting harmful effects to aquatic life

Precautionary statements

P102 Keep out of reach of children. P103 Read label before use P261 Avoid breathing dust/fume/gas/mist/vapours/spray P284 Wear respiratory protection P280 Wear protective gloves/protective clothing/eye protection/face protection P272 Contaminated work clothing should not be allowed out of the workplace. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area

Response

P304 + P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P342 + P311 IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. P302 + P352 IF ON SKIN: wash with plenty of soap and water. P333 + P313 IF SKIN irritation or rash occurs: Get medical advice/attention. P362 + P364 take off contaminated clothing and wash it before reuse P305 + P351 + P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 IF eye irritation persists: Get medical advice/attention. P304 + P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing P312 Call a POISON CENTER or doctor/physician if you feel unwell.

Storage

P405 Store locked up. P403 + P233 Store in a well-ventilated place. Keep container tightly closed

Disposal

P501 Dispose of contents/container to a waste disposal facility in accordance with local, state, federal or international laws

HMIS® ratings

HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 1 PERSONAL PROTECTIVE EQUIPMENT: G

Potential health effects

EYES: MAY CAUSE IRRITATION. SKIN: MAY CAUSE IRRITATION OR ALLERGIC SKIN RESPONSE. SKIN CONTACT MAY CAUSE SENSITIZATION. INGESTION: THIS MATERIAL HAS A PROBABLE LOW ACUTE ORAL TOXICITY. INHALATION: Harmful by inhalation. Irritating to respiratory system. May cause sensitization by inhalation.This product is a respiratory irritant and potential respiratory sensitiser: repeated inhalation of vapour or aerosol at levels above the occupational exposure limit could cause respiratory sensitisation. A hyper-reactive response to even minimal concentrations of diisocyanates may develop in sensitized persons. The onset of the respiratory symptoms may be delayed for several hours after exposure. HEALTH HAZARDS (ACUTE AND CHRONIC): THERE ARE REPORTS THAT CHRONIC EXPOSURE MAY RESULT IN PERMANENT DECREASE IN LUNG FUNCTION. SINGLE OR REPEATED SKIN CONTACT OR INHALATION MAY CAUSE SENSITIZATION OR ALLERGIC REACTION. PERSONS WITH ASTHMATIC-TYPE CONDITIONS, CHRONIC BRONCHITIS, OTHER CHRONIC RESPIRATORY DISEASES OR RECURRENT SKIN ECXEMA OR SENSITIZATION SHOULD BE EXCLUDED FROM CONTACT TO MATERIALS OR WORKING WITH THIS PRODUCTS.

Medical Conditions Generally Aggravated by Exposure

RESPIRATORY CONDITIONS OR OTHER ALLERGIC AILMENTS. CARCINOGENICITY OSHA: NO NTP: NO IARC: YES ADDITIONAL CARCINOGENICITY INFORMATION: Component Diphenylmethane 4,4'-disocyanate CAS# 101-68-8 is a IARC class 3 carcinogen