BLUE GLO

Hazard statements (CLP)

H320

Code

Statements

H320

Causes eye irritation

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Serious Eye Damage/Eye Irritation: Category 2B GHS Label Elements Signal Word: Warning Symbols: None Hazard Statements: Causes eye irritation. Precautionary Statements: Prevention: Wash hands and any exposed skin thoroughly after handling. Response: -Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Not Applicable Disposal: Not Applicable Hazards Not Otherwise Classified: Not Applicable Other Information: • May be harmful if swallowed. • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 60-100 sodium (C14-16) olefin sulfonate 68439-57-6 7-13 sodium dodecylbenzene sulfonate 25155-30-0 7-13 sodium laureth sulfate 9004-82-4 1-5 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Product does not support combustion, Use extinguishing agent suitable for type of surrounding fire Specific Hazards Arising from the Dried product is capable of burning. Combustion products are toxic. Chemical: Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full Precautions for Firefighters: protective gear. Cool fire-exposed containers with water spray. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Do not mix or use with sodium hypochlorite (bleach) or other hypochlorites. Use with these chemicals may form compounds which cause skin irritation and sensitization. Wash thoroughly after handling. Storage Conditions: Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep from freezing. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational Exposure Limits: None established. Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Not required with expected use. Skin and Body Protection: Not required with expected use. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Liquid Color: Blue Odor: Fresh pH: 6.5-7.5 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 100 °C / 212 °F Flash Point: > 100 °C / > 212 °F ASTM D56 Evaporation Rate: < 1 Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 1.04 Solubility(ies): Soluble in water Partition Coefficient: No information available. Autoignition Temperature: No information available. Decomposition Temperature: No information available. Viscosity: No information available. 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids. Hazardous Decomposition May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. Products: 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. Symptoms of Exposure: -Eye Contact: Pain, redness and swelling of the conjunctiva. -Skin Contact: Drying of the skin. -Inhalation: Nasal discomfort and coughing. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Target Organ Effects: -Eyes. Respiratory System. -Skin. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 3178 mg/kg ATEmix (dermal): 8478 mg/kg ATEmix (inhalation-dust/mist): 197.9 mg/l Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water > 90 mL/kg ( Rat ) Not Available 7732-18-5 sodium (C14-16) olefin sulfonate = 2310 mg/kg ( Rat ) = 6300 mg/kg ( Rabbit ) Not Available 68439-57-6 sodium dodecylbenzene sulfonate = 438 mg/kg ( Rat ) Not Available 25155-30-0 sodium laureth sulfate = 1600 mg/kg ( Rat ) Not Available 9004-82-4 Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Crustacea Microorganisms sodium (C14-16) olefin Not Available 1.0 - 10.0: 96 h Brachydanio Not Available sulfonate rerio mg/L LC50 static 12.2: 68439-57-6 96 h Brachydanio rerio mg/L LC50 semi-static sodium dodecylbenzene Not Available 10.8: 96 h Oncorhynchus Not Available sulfonate mykiss mg/L LC50 static 25155-30-0 Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT: Not Regulated Proper Shipping Name: Non Hazardous Product Special Provisions: Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination. Check with a trained hazardous materials transportation expert for information specific to your situation. IMDG: Not Regulated Proper Shipping Name: Non Hazardous Product 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product does not contain listed substances above the "de minimus" level SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: No Reactive Hazard: No California Proposition 65 This product is not subject to warning requirements under California Proposition 65. 16. OTHER INFORMATION NFPA Health Hazards: 1 Flammability: 0 Instability: 0 Special: N/A HMIS Health Hazards: 1 Flammability: 0 Physical Hazards: 0 Revision Date: 30-Jul-2015 Reasons for Revision: Section 14 and 15 Disclaimer: The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet

Signal word

Warning

Hazard pictograms

None

Hazard statements

Causes eye irritation.

Prevention

Wash hands and any exposed skin thoroughly after handling.

Response

-Eyes -Specific Treatment IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information.

Storage

Not Applicable

Disposal

Not Applicable

2.3 Other hazards

Not Applicable

Further information

• May be harmful if swallowed. • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children.