ALFRA

SECTION 2: Hazards identification

identification Classification of the substance or mixture Main hazards None under normal conditions Classification EC 67/548 or EC 1 999/45

2.2 Label elements

Labellinq

Hazard pictograms

None.

R-phrase(s)

None.

S-phrase(s)

None.

Other hazards

Pressurised container. To be protected against sunbeam. Do not expose to temperatures higher than 50oC. Do not pierce or burn even after use. Do not spray towards a flame or towards an incandescent object. None under normal conditions. 3.1./3.2. Substance/Preparation Preparation. This product is not considered to be hazardous and does not contain hazardous components. Preparation based on synthetic oils and additives. SECTION 4. First aid measures 4.1. Description of first aid measures General information Seek medical attention if ill effect develops. - Inhalation Assure fresh air breathing. Obtain medical attention if breathing difficulty persists. Emergency telephone number in case of poisoning: Phone: +49 (0)228-19 240 or European emergency call 112 I /8 € ALfttA Page 22/7 / 2004 ALFRA 2000 ALFRA2000-A SECTION 4. First aid measures (continued) - Skin contact Wash skin thoroughly with mild soap and water. Wash skin thoroughly with mild soap and water. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Seek medical attention if ill effect develops. - Eye contact In case of eye contact, immediately rinse with clean water for 10-15 minutes. Seek medical attention if irritation develops. - Ingestion Not expected to be a primary route of exposure. DO NOT INDUCE VOMITING. Rinse mouth. 4.2. Most important symptoms and effects, both acute and delayed - lyl5JB(j04 No information available - Skin contact No information available - Eye contact No information available - Ingestion No information available 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. 5.1. Extinquishinq media Extinguishing media - Suitable Carbon dioxide. Powder. Water fog. - Not to be used Do not use a heavy water jet. 5.2. Special arisinq from the substance or mixture Special exposure When heated to decomposition, emits dangerous fumes. (COx,...) 5.3. Advice for firefiqhters Protection against fire Use self-contained breathing apparatus when in close proximity to fire. Special procedures Do not breathe fumes from fires or vapours from thermal decomposition. Prevent fire-fighting water from entering environment. Use water stream to cool containers. Heat may build pressure, rupturing closed reciepients, spreading fire and increasing risk of burns and iniuries. SECTION 6. Accidental release measures 6.t Personal

Precautionary statements

protective equipment and emerqency procedures Personal Ventilate area. Equip cleanup crewwith proper protection. Evacuate and limit access. No smoking. 6.2. Environmental Environmental Prevent entry to sewers and public waters. Notify authorities if product enters sewers or public waters. Dispose used or damaged aerosol cans at permitted disposal sites. 6.3. Methods and material for containment and cleaninq up Emergency telephone number in case of poisoning: Phone: +49 (0)228-19 240 or European emergency call 112 2/8 S ALFRA 2000 Page ALFRA2000-A SECTION 6. Accidental release measures (continued) After spillage and/or leakage Collect spills and put it into appropriated container. Area of spillage may be slippery. Dike for recovery or absorb with appropriate material. 6.4. Reference to other sections See Heading 8 - 13. SECTION 7. Handling and storage for safe handlinq Handling Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking as well as when leaving work. Do not breathe sprayings. Container under pressure. Do not drill or burn even after use. Keep away from sources of ignition. Do not spray on naked flame or any incandescent material. Use only in well ventilated areas. Handle in accordance with good industrial hygiene and safety procedures. in handling and storage Good ventilation of the workplace required. Both local exhaust and good general room ventilation must be provided not only to control exposure but also to prevent formation of flammable mixtures. Handle in accordance with good industrial hygiene and safety procedures. 7.2. Conditions for safe storaqe, includinq any incompatibilities

Storage

Keep only in the original container in a cool, well ventilated place. Avoid releasing into the environment. Store in dry, coo1, well-ventilated area. Keep storage temperature below 50oC. - away from Heat. Open flame. Sparks. Direct sunlight. 7.3. Specific end use(s) Not applicable. SECTION 8. Exposure controls/personal protection 8.1. Control parameters Occupational Exposure Limits 8.2. Exposure controls Personal protection - Respiratory protection No special respiratory protection equipment is recommended under normal conditions of use with adequate ventilation. - Skin protection No special clothing/skin protection equipment is recommended under normal conditions of use. - Eye protection Eye protection should only be necessary where liquid could be splashed or sprayed. - Ingestion When working with the product, do not eat, drink or smoke. Industrial hygiene No special protection required where adequate ventilation is maintained. Emergency telephone number in case of poisoning: Phone: +49 (0)228-19 240 or European emergency call 112 3/8 & i 8 € & i W r :22 / 7 / 2004 ALFRA 2000 ALFRA2000-A SECTION 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties a Appearance Physical state Oily liquid. Colour Yellow-brown. * Odour Odour Characteristic. ii Odour threshold No information available Th pH value Not applicable. ii Meltinq point/Freezinq point No information available a Initial boilinq point - boilinq ranqe No information available ii Flash point Flash point [oC] > 150 ii Evaporation rate No information available a Flammability No information available - Explosion limits (lower - upper) Explosion limits - lower [%] No data available. Explosion limits - upper [%] No data available. a Vapour pressure Vapour pressure [hPa] No information available * Vapour density No information available * Relative density Density ca O,900 (active matter) * Solubility Solubility in water Material insoluble in water. @ Partition coefficient n-octanol/water No information available * Auto-iqnition temperature Auto-ignition temperature [oC] No information available a Thermal decomposition No information available - Viscosity Emergency telephone number in case of poisoning: Phone: +49 (0)228-19 240 or European emergency call 112 S ALFRA 2000 Page ALFRA2000-A SECTION 9. Physical and chemical properties (continued) Viscosity 6.2 mm2/s (40oC - active matter) a Explosive Properties No information available Not explosive according to EC criteria ii Oxidisinq properties No information available 9.2. Other information Contents under pressure. (8 bars - 20oC) SECTION 10. Stability and reactivity I O.t Reactivity None under normal conditions. 10.2. Chemical stability Stable under normal conditions of storage, handling and use. "I O.3. Possibility of hazardous reactions Hazardous reactions None under normal conditions. 10.4. Conditions to avoid Conditions to avoid Open flame. Direct sunlight. Overheating. 10.5. Incompatible materials Materials to avoid Strong acids, bases. Oxidizing agent. 10.6. Hazardous decomposition products Hazardous decomposition products When heated to decomposition, emits dangerous fumes. (COx,...) SECTION 11. Toxicological information Itl. Information on toxicoloqical effects ii On product Toxicity information No data available. ii Acute toxicity Acute toxicity Not expected to be toxic. - Inhalation Inhalation of vapours may cause respiratory irritation. - Dermal Repeated or prolonged skin contact may cause irritation. - Ocular May cause minor eye irritation. - Ingestion Not expected to be toxic. ii On components a Skin corrosion/irritation Based on available data, the classification criteria are not met. Emergency telephone number in case of poisoning: Phone: +49 (0)228-19 240 or European emergency call 112 22/7 / 2004 ALFRA 2000 ALFRA2000-A SECTION 11. Toxicological information (continued) * Serious eye damage/irritation Based on available data, the classification criteria are not met. * Respiratory or skin sensitisation Based on available data, the classification criteria are not met. @ Germ cell mutagenicity Based on available data, the classification criteria are not met. * Carcinogenicity Based on available data, the classification criteria are not met. * Reproductive toxicity Based on available data, the classification criteria are not met. * STOT-single exposure Based on available data, the classification criteria are not met. ii STOT-repeated exposure Based on available data, the classification criteria are not met. - Dermal Repeated or prolonged skin contact may cause irritation. ii Aspiration hazard Based on available data, the classification criteria are not met. 12.1. Toxicity 48 Hour-EC50 - Daphnia magna [mg/l] No data available. LC50-96 Hour - fish [mg/l] No data available. 12.2. Persistence and deqradability Biodegradation [%] Product is biodegradable. > 95 % On components 12.3. Bioaccumulative potential No information available 12.4. Mobility in soil Mobility Low mobility in the soil. Material nearly insoluble in water. 12.5. Results of PBT and vPvB assessment No information available 12.6. Other adverse effects Ecological effects information Avoid releasing into the environment. 1 3.1. Waste treatment methods Dispose in a safe manner in accordance with local/national regulations. Disposal Avoid releasing into the environment. Dispose of in a safe manner in accordance with local/national regulations. SECTION '14. Transport information

2.1 Classification of the substance or mixture

of the substance or mixture Main hazards : None under normal conditions. Classification EC 67/548 or EC 1 999/45