Note: Ingredients listed on restricted chemical lists
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
50 - 80
General Information
Revision date
2017-10-06
Product name
Task 9 EU Part A
1.2.1 Relevant identified uses
Polyurethane Elastomer
Icons in SDS
Company Information
company name
Smooth-On, Inc.
e-mail address of the competent person responsible for the Safety Data Sheet
sds@smooth-on.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
CLP CLASSIFICATION
H315 Skin corrosion/irritation – Category 2 H317 Skin sensitization – Category 1 H319 Eye irritation – Category 2A H332 Acute toxicity, inhalation – Category 4 H334 Respiratory Sensitization – Category 1 H335 Specific target organ toxicity – single exposure – Category 3 (respiratory) H351 Carcinogenicity – Category 2 H373 Specific Target Organ Toxicity, repeated exposure Category 2 (respiratory)
2.2 Label elements
REGULATION (EC) No 1272/2008)
Signal word
Danger
Health hazards
H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 May cause respiratory irritation H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. General Precautions: P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use.
Prevention
Precautions P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapors/spray. P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. P284 [In case of inadequate ventilation] wear respiratory protection.
Response
Precautions P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P311 IF exposed or concerned: Call a POISON CENTER/doctor/physician. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P314 Get medical advice/attention if you feel unwell. P332 + P313 IF SKIN irritation occurs: Get medical advice/attention. P362 + P364 Take off contaminated clothing and wash it before reuse.
Storage
Precautions P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Disposal
Precautions P501 Dispose of contents/container according to local, state and federal laws. Additional labelling requirements: EUH204 Contains isocyanates. May produce an allergic reaction.
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumula- tive and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.