Part A

Smooth-On, Inc

Revision date : 2025-02-13

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GHS08 GHS07
Health risk rating 5
Safety risk rating 1
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

202-966-0/101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

615-005- >=5% -9 >=0.1% >=5% >=5%

EC/CAS

247-714-0/26447-40-5

Name of the chemical

Methylenediphenyl diisocyanate (see also specific isomers)

Concentration

615-005- >=5% -9 >=0.1% >=5% >=5%

General Information

Revision date

2025-02-13

Product name

Part A

1.2.1 Relevant identified uses

Polyurethane Elastomer

supplier name

Smooth-On, Inc

Emergency telephone

+01-813-248-0585, 01 406 43 43, 070 245 245, +359 9154 233, +385 1 2348 342, 224 91 92 93, +45 8212 1212, 0800 147 111, +358 9 471 977, +33 01 45 42 59 59, (0030) 2107793777, +36 80 201 199, +354 543 2222, 06 3054 343, +370 (5) 2362052, +370 5 236 20 52, +370 687 533 78, (+352) 8002 5500, +31 (0) 88 755 8000, 22 59 13 00, +48 22 619 66 54, +351 800 250 250, +40 21 599 2300, +421 2 5477 4166, +34 91 562 04 20, 0344 892 0111

Icons in SDS

GHS07 GHS08

Company Information

company name

Smooth-On, Inc

e-mail address of the competent person responsible for the Safety Data Sheet

sds@smooth-on.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373, H413

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

SECTION 2: Hazards identification

Classification according to Regulation (EC) No. 1272/2008 [CLP Classification of the substance or mixture

Contains

4,4-Methylenediphenyl diisocyanate; Methylenediphenyl diisocyanate

Signal word

Danger

Hazard statements

H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H332 - Harmful if inhaled. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure. H413 - May cause long lasting harmful effects to aquatic life.

Precautionary statements

P260 - Do not breathe dust/fume/gas/mist/vapors/spray. P264 - Wash face, hands and any exposed skin thoroughly after handling. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P312 - Call a POISON CENTER or doctor if you feel unwell. P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor.

Additional information

This product requires tactile warnings if supplied to the general public.

2.3 Other hazards

No information available. Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors.

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute toxicity - Inhalation (Dusts/Mists) Category 4 - (H332) Skin corrosion/irritation Category 2 - (H315) Serious eye damage/eye irritation Category 2 - (H319) Respiratory sensitization Category 1 - (H334) Skin sensitization Category 1 - (H317) Carcinogenicity Category 2 - (H351) Specific target organ toxicity (single exposure) Category 3 - (H335) Category 3 Respiratory irritation Specific target organ toxicity (repeated exposure) Category 2 - (H373) Chronic aquatic toxicity Category 4 - (H413)

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