Poly JF Part B

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H336

Code

Statements

H315

Causes skin irritation

Classifications

Inhalation Toxicity 4 Gases>2500+<=20000ppm, Vapors>10+<=20mg/l, Dusts&mists>1+<=5mg/l Skin corrosive 2 Reversible adverse effects in dermal tissue, Draize score: >= 2.3 < 4.0 or persistent inflammation Eye corrosive 2A Eye irritant: Subcategory 2A, Reversible in 21 days Respiratory sensitizer 1 Respiratory sensitizer Skin sensitizer 1 Skin sensitizer Organ toxin single exposure 3 Transient target organ effects- Narcotic effects- Respiratory tract irritation

Hazard statements

H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H332 Harmful if inhaled H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 May cause respiratory irritation H336 May cause drowsiness or dizziness

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray P264 Wash … thoroughly after handling P271 Use only outdoors or in a well-ventilated area P272 Contaminated work clothing should not be allowed out of the workplace P280 Wear protective gloves/protective clothing/eye protection/face protection P285 In case of inadequate ventilation wear respiratory protection P312 Call a POISON CENTER or doctor/physician if you feel unwell P321 Specific treatment (see … on this label) P362 Take off contaminated clothing and wash before reuse P363 Wash contaminated clothing before reuse P302+P352 IF ON SKIN: Wash with soap and water P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing P332+P313 If skin irritation occurs: Get medical advice/attention P333+P313 If skin irritation or a rash occurs: Get medical advice/attention P337+P313 If eye irritation persists, get medical advice/attention P342+P311 Call a POISON CENTER or doctor/physician P405 Store locked up P403+P233 Store in a well ventilated place. Keep container tightly closed P501 Dispose of in accordance with all applicable local, state and federal regulations.

Signal word

Danger Acute toxicity: LD/LC50 values that are relevant for classification: 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues Oral LD50 > 2000 mg/kg (Ratte) Dermal LD50 > 9400 mg/kg (rab) (OECD- Prüfrichtlinie 402) Inhalative LC50/48 h 490 mg/l (Ratte) (als Aerosol, Exposition) · Primary irritant effect: · on the skin: Irritant to skin and mucous membranes. · on the eye: Irritating effect. · Sensitization: Sensitization possible through inhalation. Sensitization possible through skin contact.