Enamel Fix Appliance Touch-up Pen

Hazard statements (CLP)

H226, H315, H317, H319, H335, H336, H350, H360, H372

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Signal word

Danger

Hazard statements

Flammable liquid and vapor. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. May cause cancer. May damage fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure. (central nervous system (CNS), hearing organs)

Prevention

Obtain special instructions before use. Wear protective gloves. Wear protective clothing. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.

Response

Call a POISON CENTER or doctor if you feel unwell. IF exposed or concerned: Get medical advice or attention. Take off contaminated clothing and wash it before reuse. Wash contaminated clothing before reuse. IF ON SKIN Wash with plenty of water. IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention.

Storage

Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool.

Disposal

Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

Sanding and grinding dusts may be harmful if inhaled. Repeated exposure to high vapor elements concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. Avoid contact with skin and clothing. Wash thoroughly after handling. Emits toxic fumes when heated.

2.3 Other hazards

Prolonged or repeated contact may dry skin and cause irritation. Substance/mixture Mixture Product name 5.0 BASECOAT Ingredient name % CAS number n-butyl acetate ≥50 - ≤75 123-86-4 titanium dioxide ≥50 - ≤75 13463-67-7 chrome antimony titanium buff rutile ≥20 - ≤50 68186-90-3 heptan-2-one ≥20 - ≤50 110-43-0 diiron trioxide ≥20 - ≤50 1309-37-1 2-methoxy-1-methylethyl acetate ≥20 - ≤50 108-65-6 5-methylhexan-2-one ≥10 - ≤20 110-12-3 Aluminium powder (stabilized) ≥10 - ≤20 7429-90-5 butanone ≥10 - ≤20 78-93-3 D-Glucitol, 1,4:3,6-dianhydro-, 2-(4-methoxybenzoate) 5-[4-[(1-oxo-2-propen- ≥10 - ≤20 228863-31-8 1-yl)oxy]benzoate], polymer with 1,4:3,6-dianhydro-D-glucitol 5- (4-methoxybenzoate) 2-[4-[(1-oxo-2-propen-1-yl)oxy]benzoate] and 1,1'- (1,4-phenylene) bis[4-[4-[(1-oxo-2-propen-1-yl)oxy]butoxy]benzoate] D-Glucitol, 1,4:3,6-dianhydro-, bis[4-[(1- oxo-2-propenyl)oxy]benzoate], ≥10 - ≤20 260544-92-1 polymer with 1,4-phenylene bis[4-[4-[(1-oxo-2- propenyl)oxy]butoxy] benzoate] Solvent naphtha (petroleum), light aromatic ≥10 - ≤20 64742-95-6 xylene ≥10 - ≤20 1330-20-7 glass, oxide, chemicals ≥10 - ≤20 65997-17-3 Solvent naphtha (petroleum), heavy arom. ≥5.0 - ≤10 64742-94-5 Mica-group minerals ≥5.0 - ≤10 12001-26-2 aluminium oxide ≥5.0 - ≤10 1344-28-1 1,2,4-trimethylbenzene ≥5.0 - ≤10 95-63-6 carbon black, respirable powder ≥1.0 - ≤5.0 1333-86-4 Naphtha (petroleum), hydrotreated heavy ≥1.0 - ≤5.0 64742-48-9 Stoddard solvent ≥1.0 - ≤5.0 8052-41-3 [1-[[(2-hydroxyphenyl)imino]methyl]-2-naphtholato(2-)-N,O,O']copper ≥1.0 - ≤5.0 15680-42-9 Naphtha (petroleum), hydrodesulfurized heavy ≥1.0 - ≤5.0 64742-82-1 ethylbenzene ≥1.0 - ≤4.1 100-41-4 butan-1-ol ≥1.0 - <3.0 71-36-3 aluminium hydroxide ≥1.0 - ≤5.0 21645-51-2 barium sulfate ≥1.0 - ≤5.0 7727-43-7 chromium (III) oxide ≥1.0 - ≤5.0 1308-38-9 Ligroine ≥1.0 - ≤5.0 8032-32-4 quino[2,3-b]acridine-6,7,13,14(5H,12H)-tetrone ≥1.0 - ≤5.0 1503-48-6 Naphtha (petroleum), heavy alkylate ≥1.0 - ≤5.0 64741-65-7 Copper Compound ≥1.0 - ≤5.0 Not available. Naphthenic acids ≥1.0 - ≤5.0 1338-24-5 Acidic Polyester ≥1.0 - ≤5.0 Not available. toluene <1.0 108-88-3 naphthalene <1.0 91-20-3 2-methoxypropyl acetate <1.0 70657-70-4 benzyl butyl phthalate <1.0 85-68-7 cumene <1.0 98-82-8 dibutyltin oxide <1.0 818-08-6 SUB codes represent substances without registered CAS Numbers. Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8.

2.1 Classification of the substance or mixture

FLAMMABLE LIQUIDS - Category 3 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 1B TOXIC TO REPRODUCTION - Category 1B SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 100% (Oral), 100% (Dermal), 100% (Inhalation) This product contains TiO2 which has been classified as a GHS Carcinogen Category 2 based on its IARC 2B classification. For many SKM products, TiO2 is utilized as a raw material in a liquid coating formulation. In this case, the TiO2 particles are bound in a matrix with no meaningful potential for human exposure to unbound particles of TiO2 when the product is applied with a brush or roller. Sanding the coating surface or mist from spray applications may be harmful depending on the duration and level of exposure and require the use of appropriate personal protective equipment and/or engineering controls (see Section 8).