Cheetah Gold Selective Herbicide

Hazard statements (CLP)

H227, H302, H305, H315, H317, H320, H335, H351, H410

Code

Statements

H227

Combustible liquid

Hazard statements

This product is classified as: Xn, Harmful. Xi, Irritating. N, Dangerous to the environment. Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in Section 14 of this SDS. H227: Combustible liquid. H302: Harmful if swallowed. H305: May be harmful if swallowed and enters airways. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H320: Causes eye irritation. H335: May cause respiratory irritation. H351: Suspected of causing cancer. H410: Very toxic to aquatic life with long lasting effects.

SUSMP Classification

S6

ADG classification

Class 9 Miscellaneous Dangerous Goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Diclofop-Methyl/Solvent Naphtha).

Signal word

WARNING

Prevention

P102: Keep out of reach of children. P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P261: Avoid breathing fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P362: Take off contaminated clothing and wash before reuse. P301+P310 IF SWALLOWED Immediately call a POISON CENTRE or doctor P301+P312 IF SWALLOWED Call a POISON CENTRE or doctor if you feel unwell P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 If exposed or concerned Get medical advice P333+P313 If skin irritation or rash occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog. Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam can be used.

Storage

P410: Protect from sunlight. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & colour: Clear dark brown coloured liquid. Odour: Characteristic aromatic hydrocarbon odour.

Health hazards

The acute oral LD50 of Diclofop-methyl for rats ranged between 563-693 mg/kg (in sesame oil). The acute dermal LD50 for female rats was greater than 2,000 mg/kg. The no effect level (NEL) for a 90-day feeding to rats was 12.5 mg/kg and 8 mg/kg for a 15-month feeding to dogs. The acute percutaneous LD50 for rats was greater than 5,000 mg/kg. The acute inhalation toxicity for rats exposed to technical Diclofop-methyl was greater than 3.83 mg/l/hour. Rats exposed to a formulated product containing Diclofop-methyl had an oral LD50 value of greater than 2,000 mg/kg. The acute dermal LD50 for exposure to the same product was greater than 5,000 mg/kg. The inhalation LC50 in rats for a 36%EC formulation of Diclofop-methyl over a four-hour period was 8.3 mg/l air. Limited evidence of a carcinogenic effect, irritating to eyes and skin, harmful if swallowed, possible skin sensitiser, if aspirated, may cause lung damage.