Sinon Chlorpyrifos 500 EC Insecticide

Hazard statements (CLP)

H227, H301, H312, H315, H317, H320, H332, H335, H373, H410

Code

Statements

H227

Combustible liquid

Hazard statements

This product is classified as: Xi, Irritating. T, Toxic. N, Dangerous to the environment. Hazardous according to the criteria of SWA. Dangerous according to Australian Dangerous Goods (ADG) Code, IATA and IMDG/IMSBC criteria. H227: Combustible liquid. H301: Toxic if swallowed. H312: Harmful in contact with skin. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H320: Causes eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation. H373: May cause damage to organs through prolonged or repeated exposure. H410: Very toxic to aquatic life with long lasting effects.

SUSMP Classification

S6

ADG classification

Class 6.1 Toxic Substances

UN Number

3018, ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC

Signal word

DANGER Flammable liquids Category 4 Acute Toxicity Oral Category 3 Acute Toxicity Dermal Category 4 Skin Corrosion /Irritation Category 2 Skin Sensitisation Category 1 Serious eye damage/eye irritation Category 2B Acute Toxicity Inhalation Category 4 Specific Target Organ Toxicity - Single Exposure Category 3 Specific Target Organ toxicity - repeated exposure Category 2 Hazardous to aquatic environment Short term/Chronic Category 1

Prevention

P102: Keep out of reach of children. P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P260: Do not breathe fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P314: Get medical advice or attention if you feel unwell. P362: Take off contaminated clothing and wash before reuse. P301+P310 IF SWALLOWED Immediately call a POISON CENTRE or doctor P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog. Water fog or fine spray is the preferred medium for large fires.

Storage

P405: Store locked up. P410: Protect from sunlight. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Pale amber liquid. Odour: Characteristic solvent odour.

Health hazards

Chlorpyrifos is harmful to humans. Symptoms of acute exposure to organophosphate or cholinesterase-inhibiting compounds may include the following: numbness, tingling sensations, incoordination, headache, dizziness, tremor, nausea, abdominal cramps, sweating, blurred vision, difficulty breathing or respiratory depression, and slow heartbeat. Very high doses may result in unconsciousness, incontinence, and convulsions or fatality. toxic if swallowed, danger of cumulative effects, harmful by inhalation and in contact with skin, irritating to eyes and skin, possible skin sensitiser. Signs and symptoms associated with mild exposures to organophosphate and carbamate pesticides include: headache, fatigue, dizziness, loss of appetite with nausea, stomach cramps and diarrhoea; blurred vision associated with excessive tearing; contracted pupils of the eye; excessive sweating and salivation; slowed heartbeat, often fewer than 50 per minute; rippling of surface muscles just under the skin. These symptoms may be mistaken for those of flu, heat stroke or heat exhaustion, or upset stomach. Moderately severe organophosphate and carbamate insecticide poisoning cases exhibit all the signs and symptoms found in mild poisonings, but in addition, the victim: is unable to walk; often complains of chest discomfort and tightness; exhibits marked constriction of the pupils (pinpoint pupils); exhibits muscle twitching; has involuntary urination and bowel movement. Severe poisonings are indicated by incontinence, unconsciousness and seizures.