Sinon Chloro 720 Fungicide

Hazard statements (CLP)

H315, H317, H319, H330, H335, H351, H410

Code

Statements

H315

Causes skin irritation

Hazard statements

This product is classified as: Xi, Irritating. T, Toxic. N, Dangerous to the environment. Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in Section 14 of this SDS. R26, R37, R40, R41, R43, R50/53. Very toxic by inhalation. Irritating to respiratory system. Limited evidence of a carcinogenic effect. Risk of serious damage to eyes. May cause sensitisation by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects to the aquatic environment. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H330: Fatal if inhaled. H335: May cause respiratory irritation. H351: Suspected of causing cancer. H410: Very toxic to aquatic life with long lasting effects.

Precautionary statements

S2, S23, S26, S28, S38, S45, S60, S61, S24/25, S36/37. Keep out of reach of children. Do not breathe vapours or mists. In case of contact with eyes, rinse immediately with plenty of water and contact a doctor or Poisons Information Centre. After contact with skin, wash immediately with plenty of soap and water. In case of insufficient ventilation, wear suitable respiratory equipment. In case of accident or if you feel unwell, contact a doctor or Poisons Information Centre immediately (show this SDS where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/Safety Data Sheets. Avoid contact with skin and eyes. Wear suitable protective clothing and gloves.

SUSMP Classification

S6

ADG classification

Class 9 Miscellaneous dangerous goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

DANGER

Prevention

P202: Do not handle until all safety precautions have been read and understood. P260: Do not breathe fumes, mists, vapours or spray. P264: Wash contacted areas thoroughly after handling. P271: Use only outdoors or in a well ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P281: Use personal protective equipment as required.

Response

P310: Immediately call a POISON CENTER or doctor/physician. P320: Specific treatment is urgent (see First Aid section of this SDS. P362: Take off contaminated clothing and wash before reuse. P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 If exposed or concerned Get medical advice P333+P313 If skin irritation or rash occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog.

Storage

P405: Store locked up. P403+P233: Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: White liquid. Odour: No data re odour.

Health hazards

Chlorothalonil can cause severe eye and skin irritation in certain formulations. Very high doses may cause a loss of muscle coordination, rapid breathing, nose bleeding, vomiting, hyperactivity, and death. Dermatitis, vaginal bleeding, bright yellow and/or bloody urine, and kidney tumours may also occur. This product is very toxic by inhalation, limited evidence of a carcinogenic effect, may cause serious damage to eyes, respiratory tract irritant, possible skin sensitiser.

Potential health effects

Persons sensitised to Chlorothalonil should avoid contact with this product. Inhalation: Short Term Exposure: Available data shows that this product is very toxic, but symptoms are not available. In addition product is an inhalation irritant. Symptoms may include headache, irritation of nose and throat and increased secretion of mucous in the nose and throat. Other symptoms may also become evident, but they should disappear after exposure has ceased. Long Term Exposure: No data for health effects associated with long term inhalation. Skin Contact: Short Term Exposure: Classified as a potential sensitiser by skin contact. Exposure to a skin sensitiser, once sensitisation has occurred, may manifest itself as skin rash or inflammation, and in some individuals this reaction can be severe. In addition product may be irritating, but is unlikely to cause anything more than mild transient discomfort. Long Term Exposure: No data for health effects associated with long term skin exposure. Eye Contact: Short Term Exposure: This product is a severe eye irritant. Symptoms may include stinging and reddening of eyes and watering which may become copious. Other symptoms such as swelling of eyelids and blurred vision may also become evident. If exposure is brief, symptoms should disappear once exposure has ceased. However, lengthy exposure or delayed treatment is likely to cause permanent damage. Long Term Exposure: No data for health effects associated with long term eye exposure. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product is an oral irritant. Symptoms may include burning sensation and reddening of skin in mouth and throat. Other symptoms may also become evident, but all should disappear once exposure has ceased. Long Term Exposure: No data for health effects associated with long term ingestion. Carcinogen Status: SWA: Chlorothalonil is classified by SWA as a Class 3 Carcinogen, possibly carcinogenic to humans. See the SWA website for further details. A web address has not been provided as addresses frequently change. NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: Chlorothalonil is classed 2b IARC - possibly carcinogenic to humans. See the IARC website for further details. A web address has not been provided as addresses frequently change.