Chieftain Duo 100EC Insecticide

Hazard statements (CLP)

H302, H315, H320, H336, H373, H410

Code

Statements

H302

Harmful if swallowed

Hazard statements

This product is classified as: Xn, Harmful. Xi, Irritating. N, Dangerous to the environment. Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in Section 14 of this SDS. AUH066: Repeated exposure may cause skin dryness or cracking. H302: Harmful if swallowed. H315: Causes skin irritation. H320: Causes eye irritation. H336: May cause drowsiness or dizziness. H373: May cause damage to organs through prolonged or repeated exposure. H410: Very toxic to aquatic life with long lasting effects.

SUSMP Classification

S6

ADG classification

Class 9 Miscellaneous dangerous goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

WARNING Acute Toxicity Oral Category 4 Skin Corrosion /Irritation Category 2 Serious eye damage/eye irritation Category 2B Specific Target Organ Toxicity - Single Exposure Category 3 Specific Target Organ toxicity - repeated exposure Category 2 Hazardous to aquatic environment Short term/Chronic Category 1

Prevention

P260: Do not breathe fumes, mists, vapours or spray. P261: Avoid breathing fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P312: Call a POISON CENTER or doctor if you feel unwell. P362: Take off contaminated clothing and wash before reuse. P301+P312 IF SWALLOWED Call a POISON CENTER or doctor if you feel unwell P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 If skin irritation occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog.

Storage

P405: Store locked up. P410: Protect from sunlight. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Clear, straw coloured liquid. Odour: Characteristic hydrocarbon solvent odour.

Health hazards

The onset of symptoms varies depending upon such factors as the route of absorption and quantity involved. In patients with occupational poisoning, skin symptoms usually develop within 4-6 hours after exposure, with systemic symptoms occurring as late as 48 hours after exposure. Paraesthesia of the facial skin can develop approximately 30 minutes after exposure and does not usually last beyond 24 hours when exposure is terminated. Following ingestion, the initial symptoms involve the gastrointestinal tract, developing 10-60 minutes after exposure. Patients suffering from acute oral poisoning usually develop prominent digestive symptoms such as epigastric pain, nausea and vomiting. Severely poisoned patients may have frequent convulsive attacks, coma, or pulmonary oedema. The prognosis is good if treated, with usually full recovery even in severely poisoned patients. (The hospitalisation period is usually longer than 4 weeks). Death may occur from respiratory paralysis. This product is irritating to eyes and skin, harmful if swallowed, repeated exposure may cause skin dryness or cracking, vapours may cause drowsiness and dizziness.