850CF Part A ISO

Hazard statements (CLP)

H315, H317, H319, H334, H335, H373

Code

Statements

H315

Causes skin irritation

2.1 Classification of the substance or mixture

d ~  GHS08 Health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. d ~  GHS07 Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2A H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H335 May cause respiratory irritation.

2.2 Label elements

The product is classified and labeled according to the Globally Harmonized System (GHS).

Hazard pictograms

d ~  d ~  GHS07 GHS08

Signal word

Danger

Hazardous Ingredients

4,4'-methylenediphenyl diisocyanate Diphenylmethanediisocyanate, isomeres and homologues o-(p-isocyanatobenzyl)phenyl isocyanate

Hazard statements

H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapors/spray. P284 [In case of inadequate ventilation] wear respiratory protection. P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves. P280 Wear eye protection / face protection. P264 Wash thoroughly after handling. P272 Contaminated work clothing must not be allowed out of the workplace. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 Specific treatment (see supplementary first aid instructions on this Safety Data Sheet). P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTER/doctor if you feel unwell. P363 Wash contaminated clothing before reuse. P304+P341 If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. P332+P313 If skin irritation occurs: Get medical advice/attention. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P314 Get medical advice/attention if you feel unwell. P302+P352 IF ON SKIN: Wash with plenty of water. P362+P364 Take off contaminated clothing and wash it before reuse. P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Unknown acute toxicity: 30 % of the mixture consists of component(s) of unknown toxicity.

Classification system

NFPA ratings (scale 0 - 4) Health = 1 1 Fire = 1 1 0 Reactivity = 0 · HMIS-ratings (scale 0 - 4) HEALTH *1 Health = *1 FIRE 1 Fire = 1 REACTIVITY 0 Reactivity = 0

2.3 Other hazards

None known