Note: Ingredients listed on restricted chemical lists
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
>=10-<20
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
>=10-<20
General Information
Revision date
2019-01-21
Product name
SikaBond Rapid DPM
supplier name
Sika Limited
Icons in SDS
Company Information
company name
Sika Limited
e-mail address of the competent person responsible for the Safety Data Sheet
EHS@uk.sika.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
CLP CLASSIFICATION
Acute toxicity, Category 4 H332: Harmful if inhaled. Skin irritation, Category 2 H315: Causes skin irritation. Eye irritation, Category 2 H319: Causes serious eye irritation. Respiratory sensitisation, Category 1 H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin sensitisation, Category 1 H317: May cause an allergic skin reaction. Carcinogenicity, Category 2 H351: Suspected of causing cancer. Specific target organ toxicity - single ex- H335: May cause respiratory irritation. posure, Category 3, Respiratory system Specific target organ toxicity - repeated H373: May cause damage to organs through pro- exposure, Category 2 longed or repeated exposure.
2.2 Label elements
REGULATION (EC) No 1272/2008)
Signal word
Danger
Hazard statements
H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through pro- longed or repeated exposure.
Precautionary statements
P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children.
Prevention
P260 Do not breathe dust/ fume/ gas/ mist/ va- pours/ spray. P271 Use only outdoors or in a well-ventilated ar- ea. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 In case of inadequate ventilation wear respir- atory protection.
Response
P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P308 + P313 IF exposed or concerned: Get medical ad- vice/ attention.
Storage
P405 Store locked up.
Disposal
P501 Dispose of contents/container in accordance with local regulation.
Hazardous Ingredients
4,4'-methylenediphenyl diisocyanate Diphenylmethanediisocyanate, isomeres and homologues Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'- methylenebis[isocyanatobenzene] Reaction mass of 4,4'-methylenediphenyl diisocyanate and o-(pisocyanatobenzyl) phenyl isocyanate Benzene, 1,1'-methylenebis[4-isocyanato-,homopolymer, polymer with 1,2- ethanediamine, methyloxirane and oxirane
Additional information
EUH204 Contains isocyanates. May produce an allergic reaction. Persons already sensitised to diisocyanates may develop allergic reactions when using this product. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used.
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.