Sikalastic -612

Sika Hellas ABEE

Revision date : 2023-04-21

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GHS02 GHS08 GHS07
Health risk rating 5
Safety risk rating 3
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

918-668-5/13463-67-7

Name of the chemical

Reaction mass of titanium dioxide and silver chloride

Concentration

>=10-<20 >=5-<10

EC/CAS

261-879-6/9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

=1-<2,5 >=5% >=0,1% >=5% >=5%

EC/CAS

202-966-0/101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

>=0,1-<1 >=5% >=5% >=5% >=0,1%

EC/CAS

227-534-9/5873-54-1

Name of the chemical

2,4’-Methylenediphenyl diisocyanate

Concentration

>=0,1-<1 >=5% >=5% >=5% >=0,1%

EC/CAS

945-730-9/2536-05-2

Name of the chemical

2,2’-Methylenediphenyl diisocyanate

Concentration

<0,1

EC/CAS

236-675-5

Name of the chemical

Titandioxid; [in Pulverform mit mindestens 1 % Partikel mit aerodynamischem Durchmesser ≤ 10 μm] (2020/217)

Concentration

>=2,5-<5

EC/CAS

219-799-4

Name of the chemical

4,4'-Methylendiphenyldiisocyanat 2,2'-Methylendiphenyldiisocyanat 2,4'-Methylendiphenyldiisocyanat Methylendiphenyldiisocyanat (790/2009)

Concentration

>=5% >=5% >=5% >=0,1%

General Information

Version

6.1

Revision date

2023-04-21

Product name

Sikalastic -612

1.2.1 Relevant identified uses

Polyurethane coating

supplier name

Sika Hellas ABEE

Emergency telephone

+30 210 81 60 600, +30 210 81 60 606, 30 210 77 93 777

Icons in SDS

GHS02 GHS07 GHS08 M004 M008 M009 M010 M011 M017

Company Information

company name

Sika Hellas ABEE

e-mail address of the competent person responsible for the Safety Data Sheet

EHS@gr.sika.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H317, H334, H335, H351, H412

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapour. H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H412 Harmful to aquatic life with long lasting ef- fects.

Precautionary statements

P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children.

Prevention

P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing mist or vapours. P271 Use only outdoors or in a well-ventilated ar- ea. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P308 + P313 IF exposed or concerned: Get medical ad- vice/ attention. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

Storage

P405 Store locked up.

Disposal

P501 Dispose of contents/container in accordance with local regulation.

Hazardous Ingredients

Hydrocarbons, C9, aromatics bis[2-[2-(1-methylethyl)-3-oxazolidinyl]ethyl] hexane-1,2-diylbiscarbamate Diphenylmethanediisocyanate, isomeres and homologues 4,4'-methylenediphenyl diisocyanate o-(p-isocyanatobenzyl)phenyl isocyanate 4-morpholinecarbaldehyde 2,2'-methylenediphenyl diisocyanate

Additional information

EUH211 Warning! Hazardous respirable droplets may be formed when sprayed. Do not breathe spray or mist. "As from 24 August 2023 adequate training is required before industrial or pro- fessional use." Persons already sensitised to diisocyanates may develop allergic reactions when using this product. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to stand- ard EN 14387) is used.

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have en- docrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regula- tion (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 3 H226: Flammable liquid and vapour. Respiratory sensitisation, Category 1 H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin sensitisation, Category 1 H317: May cause an allergic skin reaction. Carcinogenicity, Category 2 H351: Suspected of causing cancer. Specific target organ toxicity - single ex- H335: May cause respiratory irritation. posure, Category 3, Respiratory system Long-term (chronic) aquatic hazard, Cat- H412: Harmful to aquatic life with long lasting ef- egory 3 fects.

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