Part B

Sika Australia Pty. Ltd

Revision date : 2024-09-17

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GHS08 GHS07
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

>=30-<60

EC/CAS

9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

>=30-<60

EC/CAS

5873-54-1

Name of the chemical

2,4’-Methylenediphenyl diisocyanate

Concentration

>=10-<20

General Information

Version

1.0

Revision date

2024-09-17

Product name

Part B

1.2.1 Relevant identified uses

Sealing system, For professional users only

Emergency telephone

+61 1800 033 111, +61 2 9725 33 30

Icons in SDS

GHS07 GHS08

Company Information

company name

Sika Australia Pty. Ltd

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

SECTION 2: Hazards identification

GHS Classification GHS Classification Acute toxicity (Inhalation) Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irri- tation Category 2A Respiratory sensitisation Category 1 Skin sensitisation Category 1 Carcinogenicity Category 2 Specific target organ toxicity - Category 3 (Respiratory system) single exposure Specific target organ toxicity - repeated exposure (Inhala- tion) Category 2

Signal word

Danger

Hazard statements

H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or re- peated exposure if inhaled.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe mist or vapours. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/ protective clothing/ eye protec- tion/ face protection/ hearing protection. P284 Wear respiratory protection.

Response

P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash occurs: Get medical ad- vice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ at- tention. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER/ doctor. P362 + P364 Take off contaminated clothing and wash it before reuse.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Acute toxicity (Inhalation) : Category 4 Skin corrosion/irritation : Category 2 Serious eye damage/eye irri- : Category 2A tation Respiratory sensitisation : Category 1 Skin sensitisation : Category 1 Carcinogenicity : Category 2 Specific target organ toxicity - : Category 3 (Respiratory system) single exposure Specific target organ toxicity - : Category 2 repeated exposure (Inhala- tion)

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