Note: Ingredients listed on restricted chemical lists
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
50-100%
EC/CAS
204-881-4/128-37-0
Name of the chemical
2,6-di-tert-butyl-p-cresol
Concentration
≥0.1-<0.25%
General Information
Revision date
2020-01-04
Product name
PX1000 Part A Isocyanate
1.2.1 Relevant identified uses
Polyurethane resin
supplier name
Sika Advanced Resins, US
Emergency telephone
+1 (248) 588-2270, +1 (800) 424-9300
Icons in SDS
Company Information
company name
Sika Advanced Resins, US
e-mail address of the competent person responsible for the Safety Data Sheet
ehs-us@axson.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
NFPA Rating Classification of the substance or mixture GHS08 Health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Carc. 2 H351 Suspected of causing cancer STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure GHS07 Acute Tox. 4 H332 Harmful if inhaled Skin Irrit. 2 H315 Causes skin irritation Eye Irrit. 2A H319 Causes serious eye irritation Skin Sens. 1 H317 May cause an allergic skin reaction STOT SE 3 H335 May cause respiratory irritation
2.2 Label elements
The product is classified and labeled according to the Globally Harmonized System (GHS) (Contd. of page 1)
Hazard pictograms
GHS07 GHS08
Signal word
Danger
Hazardous Ingredients
4,4'-methylenediphenyl diisocyanate Homopolymer of methylenediphenyl diisocyanate
Hazard statements
Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of causing cancer. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray Do not breathe dust/fume/gas/mist/vapors/spray. Wear protective gloves/protective clothing/eye protection/face protection. [In case of inadequate ventilation] wear respiratory protection. IF INHALED: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. If experiencing respiratory symptoms: Call a poison center/doctor. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system
· NFPA ratings (scale 0 - 4) Health = 2 1 Fire = 1 2 0 Reactivity = 0 · HMIS-ratings (scale 0 - 4) HEALTH *2 Health = *2 FIRE 1 Fire = 1 REACTIVITY 0 Reactivity = 0 (Contd. of page 2)
PBT Substances
Not applicable
vPvB Substances
Not applicable *
2.1 Classification of the substance or mixture
GHS08 Health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Carc. 2 H351 Suspected of causing cancer. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. GHS07 Acute Tox. 4 H332 Harmful if inhaled. Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2A H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H335 May cause respiratory irritation.
