Note: Ingredients listed on restricted chemical lists
EC/CAS
229-962-1/6864-37-5
Name of the chemical
2,2'-dimethyl-4,4'-methylenebis(cyclohexylamine)
Concentration
20-50%
EC/CAS
270-877-4/68479-98-1
Name of the chemical
Diethylmethylbenzenediamine
Concentration
20-50%
EC/CAS
217-168-8/1761-71-3
Name of the chemical
bis(4-aminocyclohexyl)methane
Concentration
20-50% 5-10% ≥5-<10%
EC/CAS
210-484-7/616-47-7
Name of the chemical
1-methylimidazole
Concentration
≥1-<5%
EC/CAS
220-666-8/2855-13-2
Name of the chemical
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Concentration
≥0.1-<1%
EC/CAS
247-134-8/25513-64-8
Name of the chemical
mixture of (35-45 % w/w) 1,6-diamino-2,2,4-trimethylhexane and (55-65 % w/w)1,6-diamino-2,4,4-trimethylhexane
Concentration
≥0.1-<1%
General Information
Revision date
2020-03-04
Product name
EC433-3 Hardener
supplier name
Sika Advanced Resins, US
Emergency telephone
+1 (248) 588-2270, +1 (800) 424-9300
Icons in SDS
Company Information
company name
Sika Advanced Resins, US
e-mail address of the competent person responsible for the Safety Data Sheet
advancedresins.ehs@us.sika.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H301, H311, H314, H317, H318, H330, H334, H373
Hazard statements
Code
Statements
H301
Toxic if swallowed
Section 2
SECTION 2: Hazards identification
NFPA Rating Classification of the substance or mixture GHS06 Skull and crossbones Acute Tox. 3 H301 Toxic if swallowed Acute Tox. 3 H311 Toxic in contact with skin Acute Tox. 2 H330 Fatal if inhaled GHS08 Health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure GHS05 Corrosion Skin Corr. 1A H314 Causes severe skin burns and eye damage Eye Dam. 1 H318 Causes serious eye damage Contd. on page 2) US Contd. of page 1) GHS07 Skin Sens. 1 H317 May cause an allergic skin reaction
2.2 Label elements
The product is classified and labeled according to the Globally Harmonized System (GHS)
Hazard pictograms
GHS05 GHS06 GHS08
Signal word
Danger
Hazardous Ingredients
2,2'-dimethyl-4,4'methylenebis(cyclohexylamine) Aromatic amine epoxy adduct - trade secret Methyleneoxide, polymer with benzenamine, hydrogenated 4,4'-methylenebis(cyclohexylamine) 3-aminomethyl-3,5,5-trimethylcyclohexylamine 1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
Hazard statements
Toxic if swallowed or in contact with skin. Fatal if inhaled. Causes severe skin burns and eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray Do not breathe dusts or mists. Wear protective gloves/protective clothing/eye protection/face protection. [In case of inadequate ventilation] wear respiratory protection. If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see on this label). Take off immediately all contaminated clothing and wash it before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. (Contd. on page 3) US (Contd. of page 2)
Classification system
ꞏ NFPA ratings (scale 0 - 4) Health = 3 1 Fire = 1 3 0 Reactivity = 0 ꞏ HMIS-ratings (scale 0 - 4) HEALTH *3 Health = *3 FIRE 1 Fire = 1 REACTIVITY 0 Reactivity = 0
PBT Substances
Not applicable
vPvB Substances
Not applicable *
2.1 Classification of the substance or mixture
GHS06 Skull and crossbones Acute Tox. 3 H301 Toxic if swallowed. Acute Tox. 3 H311 Toxic in contact with skin. Acute Tox. 2 H330 Fatal if inhaled. GHS08 Health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. GHS05 Corrosion Skin Corr. 1A H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage. (Contd. on page 2) US (Contd. of page 1) GHS07 Skin Sens. 1 H317 May cause an allergic skin reaction.
