SIGMALINE 855 REPAIR HARDENER

ndpic@sfda.gov. sa

Revision date : 2020-02-21

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GHS02 GHS07 GHS08
Health risk rating 5
Safety risk rating 2
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

N/A

EC/CAS

101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

N/A

EC/CAS

1330-20-7

Name of the chemical

Xylene

Concentration

N/A

Listed in

EC/CAS

5873-54-1

Name of the chemical

2,4’-Methylenediphenyl diisocyanate

Concentration

N/A

EC/CAS

100-41-4

Name of the chemical

Ethylbenzene

Concentration

N/A

Listed in

EC/CAS

2536-05-2

Name of the chemical

2,2’-Methylenediphenyl diisocyanate

Concentration

N/A

EC/CAS

26471-62-5

Name of the chemical

m-Tolylidendiisocyanat

Concentration

N/A

EC/CAS

202-966-0

Name of the chemical

4,4'-Methylendiphenyldiisocyanat 2,2'-Methylendiphenyldiisocyanat 2,4'-Methylendiphenyldiisocyanat Methylendiphenyldiisocyanat (790/2009)

Concentration

N/A

EC/CAS

227-534-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat 2,2'-Methylendiphenyldiisocyanat 2,4'-Methylendiphenyldiisocyanat Methylendiphenyldiisocyanat (790/2009)

Concentration

N/A

EC/CAS

219-799-4

Name of the chemical

4,4'-Methylendiphenyldiisocyanat 2,2'-Methylendiphenyldiisocyanat 2,4'-Methylendiphenyldiisocyanat Methylendiphenyldiisocyanat (790/2009)

Concentration

N/A

EC/CAS

247-722-4

Name of the chemical

m-Tolylidendiisocyanat

Concentration

N/A

General Information

Revision date

2020-02-21

Product name

SIGMALINE 855 REPAIR HARDENER

1.2.2. Uses advised against

Product is not intended, labelled or packaged for consumer use

supplier name

ndpic@sfda.gov. sa

Emergency telephone

00966 138473100 extn 1001

Icons in SDS

Company Information

company name

ndpic@sfda.gov. sa

e-mail address of the competent person responsible for the Safety Data Sheet

ndpic@sfda.gov.sa

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H315, H317, H319, H332, H334, H335, H351, H373

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

1272/2008]

Product definition

Mixture

CLP CLASSIFICATION

Flam. Liq. 3, H226 Acute Tox. 4, H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Resp. Sens. 1, H334 Skin Sens. 1, H317 Carc. 2, H351 STOT SE 3, H335 STOT RE 2, H373 The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended. See Section 16 for the full text of the H statements declared above. See Section 11 for more detailed information on health effects and symptoms.

Signal word

Danger

Hazard statements

Flammable liquid and vapour. Harmful if inhaled. Causes serious eye irritation. Causes skin irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of causing cancer. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.

Prevention

Wear protective gloves. Wear protective clothing. Wear eye or face protection. Wear respiratory protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not breathe vapour.

Response

IF INHALED: Remove person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or physician. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Storage

Store in a well-ventilated place. Keep cool.

Disposal

Not applicable.

Hazardous Ingredients

Toluene diisocyanate, oligomeric reaction products with 2,2'-oxydiethanol and propylidenetrimethanol Isocyanic acid, polymethylenepolyphenylene ester 4,4'-methylenediphenyl diisocyanate o-(p-isocyanatobenzyl)phenyl isocyanate 2,2'-methylenediphenyl diisocyanate Additives m-tolylidene diisocyanate

Supplemental label elements

Contains isocyanates. May produce an allergic reaction. elements

Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles

Not applicable.

Special packaging requirements

Containers to be fitted Not applicable. with child-resistant fastenings

Tactile warning of danger

Not applicable.

2.3 Other hazards

Product meets the criteria : This mixture does not contain any substances that are assessed to be a PBT or a for PBT or vPvB vPvB.

Other hazards which do not result in classification

Prolonged or repeated contact may dry skin and cause irritation.

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