Sodium sulfide

Sigma-Aldrich

Revision date : 2015-08-25

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GHS02 GHS05 GHS06 GHS09
Health risk rating 4
Safety risk rating 5
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

1313-82-2

Name of the chemical

Disodium sulphide

Concentration

N/A

General Information

Revision date

2015-08-25

Product name

Sodium sulfide

CAS No.

1313-82-2

Emergency telephone

(314) 776-6555

Icons in SDS

Company Information

company name

Sigma-Aldrich

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H251, H290, H301, H301+H311, H311, H314, H318, H400

Hazard statements

Code

Statements

H251

Self-heating; may catch fire

Section 2

OSHA HCS Classification

Self-heating substances and mixtures (Category 1), H251 Corrosive to metals (Category 1), H290 Acute toxicity, Oral (Category 3), H301 Acute toxicity, Dermal (Category 3), H311 Skin corrosion (Category 1B), H314 Serious eye damage (Category 1), H318 Acute aquatic toxicity (Category 1), H400 For the full text of the H-Statements mentioned in this Section, see Section 16.

Signal word

Danger

Hazard statements

H251 Self-heating: may catch fire. H290 May be corrosive to metals. H301 + H311 Toxic if swallowed or in contact with skin H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H400 Very toxic to aquatic life.

Precautionary statements

P234 Keep only in original container. P235 + P410 Keep cool. Protect from sunlight. P260 Do not breathe dust or mist. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. Rinse mouth. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. P362 Take off contaminated clothing and wash before reuse. P390 Absorb spillage to prevent material damage. P391 Collect spillage. P405 Store locked up. P406 Store in corrosive resistant stainless steel container with a resistant inner liner. P407 Maintain air gap between stacks/ pallets. P413 Store bulk masses greater than .? kg/ .? lbs at temperatures not exceeding .? °C/ .? °F. P420 Store away from other materials. P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Other hazards

Contact with acids liberates toxic gas., Corrosive to the respiratory tract.

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