Residual Solvents, California Mix Categories I and II

Sigma-Aldrich Chemie GmbH

Revision date : 2024-01-16

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GHS07 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

204-826-4/127-19-5

Name of the chemical

N,N-dimethylacetamide (DMAC)

Concentration

>=90-< 100%

EC/CAS

203-777-6/110-54-3

Name of the chemical

n-Hexan (790/2009)

Concentration

>=0,25-<1

EC/CAS

200-659-6/67-56-1

Name of the chemical

Methanol

Concentration

603-001-

EC/CAS

203-625-9/108-88-3

Name of the chemical

Toluene

Concentration

>=0,25-<1

EC/CAS

200-838-9/75-09-2

Name of the chemical

Methylene chloride

Concentration

>=0,1-<1

EC/CAS

203-458-1/107-06-2

Name of the chemical

1,2-Dichloroethane; ethylene dichloride

Concentration

>=0,1-<1

EC/CAS

200-663-8/67-66-3

Name of the chemical

Chloroform

Concentration

>=0,1-<1

EC/CAS

201-167-4/79-01-6

Name of the chemical

Trichloroethylene

Concentration

>=0,1-< 0,25%

General Information

Version

8.3

Revision date

2024-01-16

Product name

Residual Solvents, California Mix Categories I and II

REACH No

This

Emergency telephone

0800 181 7059 (CHEMTREC Deutschland

Icons in SDS

GHS07 GHS08

Company Information

company name

Sigma-Aldrich Chemie GmbH

e-mail address of the competent person responsible for the Safety Data Sheet

technischerservice@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H312, H312+H332, H319, H332, H340, H350, H360D, H412

Hazard statements

Code

Statements

H312

Harmful in contact with skin

H312+H332

Harmful in contact with skin or if inhaled

H319

Causes serious eye irritation

H332

Harmful if inhaled

H340

May cause genetic defects

H350

May cause cancer

H360D

May damage the unborn child.

H412

Harmful to aquatic life with long lasting effects

Section 2

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Acute toxicity, (Category 4) H332: Harmful if inhaled. Acute toxicity, (Category 4) H312: Harmful in contact with skin. Eye irritation, (Category 2) H319: Causes serious eye irritation. Germ cell mutagenicity, H340: May cause genetic defects. (Category 1B) Carcinogenicity, (Category 1A) H350: May cause cancer. Reproductive toxicity, (Category H360D: May damage the unborn child. 1B) Long-term (chronic) aquatic H412: Harmful to aquatic life with long hazard, (Category 3) lasting effects.

2.2 Label elements

Labelling

Signal word

Danger Danger

Hazard statements

H312 + H332 Harmful in contact with skin or if inhaled. H319 Causes serious eye irritation. H340 May cause genetic defects. H350 May cause cancer. H360D May damage the unborn child. H412 Harmful to aquatic life with long lasting effects. EUH208 H340 May cause genetic defects. H350 May cause cancer. H412 Harmful to aquatic life with long lasting effects. H360D May damage the unborn child.

Precautionary statements

P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P302 + P352 + P312 IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/ doctor if you feel unwell. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P308 + P313 IF exposed or concerned: Get medical advice/ attention.

Supplemental label elements

none none

Contains

trichloroethylene. May produce an allergic reaction Restricted to professional users. For use in industrial installations only. Reduced Labeling (<= 125 ml)

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

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