Phenyllithium (20% solution in dibutylether)

Sigma-Aldrich Pte Ltd

Revision date : 2021-07-01

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GHS02 GHS05 GHS07 GHS08 GHS09
Health risk rating 5
Safety risk rating 2
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

64742-49-0

Name of the chemical

Naphtha (petroleum), hydrotreated light

Concentration

N/A

General Information

Revision date

2021-07-01

Product name

Phenyllithium (20% solution in dibutylether)

Icons in SDS

Company Information

company name

Sigma-Aldrich Pte Ltd

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H314, H318, H335, H340, H350, H373, H411

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

2.1 Classification of the substance or mixture

Flammable liquids (Category 3), H226 Skin corrosion/irritation (Category 1), H314 Serious eye damage/eye irritation (Category 1), H318 Germ cell mutagenicity (Category 1B), H340 Carcinogenicity (Category 1A), H350 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Specific target organ toxicity - repeated exposure (Category 2), Blood, H373 Long-term (chronic) aquatic hazard (Category 2), H411 For the full text of the H-Statements mentioned in this Section, see Section 16.

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapor. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H340 May cause genetic defects. H350 May cause cancer. H373 May cause damage to organs (Blood) through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects.

Prevention

P201 Obtain special instructions before use. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P391 Collect spillage.

2.3 Other hazards

Reacts violently with water.

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