General Information
Version
8.11
Revision date
2025-03-27
Product name
Lithium aluminium hydride (tablets) for syn- thesis
CAS No.
16853-85-3
1.2.1 Relevant identified uses
Intermediate for use under strictly controlled conditions 1.4
Emergency telephone
+65 6890 6633, +65 6890 6639, +65 3158 1349
Icons in SDS
Company Information
company name
Sigma-Aldrich Pte Ltd
e-mail address of the competent person responsible for the Safety Data Sheet
TechnicalService@merckgroup.com
GHS Information
Signal word
none
Hazard Codes
Hazard statements (CLP)
H260, H314
Hazard statements
Code
Statements
H260
In contact with water releases flammable gases which may ignite spontaneously
Section 2
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Substances and mixtures which in contact with wa- ter emit flammable gases : Category 1 Skin corrosion/irritation : Category 1A Serious eye damage/eye irritation : Category 1
Signal word
Danger none
Hazard statements
H260 In contact with water releases flammable gases which may ignite spontaneously. H314 Causes severe skin burns and eye damage. none
Prevention
P231 + P232 Handle under inert gas. Protect from moisture. P260 Do not breathe dusts or mists. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immedi- ately call a POISON CENTER/ doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cau- tiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P335 + P334 Brush off loose particles from skin. Im- merse in cool water/ wrap in wet bandages. P370 + P378 In case of fire: Use dry sand, dry chemi- cal or alcohol-resistant foam to extinguish. Reduced Labeling (<= 125 ml)
Precautionary statements
none Refer to the Safety Data Sheet before use.
Other hazards which do not result in classification
None known.
