Diisobutylaluminum hydride solution

Sigma-Aldrich Pte Ltd

Revision date : 2023-10-19

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GHS07 GHS02 GHS08
Health risk rating 4
Safety risk rating 4
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

General Information

Version

8.8

Revision date

2023-10-19

Product name

Diisobutylaluminum hydride solution

1.2.1 Relevant identified uses

For R&D use only. Not for pharmaceutical, household or other uses

Emergency telephone

+65 6890 6633, +65 6890 6639, +65 3158 1349

Icons in SDS

GHS02 GHS07 GHS08

Company Information

company name

Sigma-Aldrich Pte Ltd

e-mail address of the competent person responsible for the Safety Data Sheet

TechnicalService@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H250, H260, H304, H314, H336, H361, H373

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Flammable liquids (Category 2), H225 Pyrophoric liquids (Category 1), H250 Substances and mixtures which in contact with water emit flammable gases (Category 1), H260 Skin corrosion/irritation (Category 1), H314 Serious eye damage/eye irritation (Category 1), H318 Reproductive toxicity (Category 2), H361 Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336 Specific target organ toxicity - repeated exposure, Inhalation (Category 2), Central nervous system, H373 Aspiration hazard (Category 1), H304 For the full text of the H-Statements mentioned in this Section, see Section 16.

Aspiration hazard

(Category 1), H304 For the full text of the H-Statements mentioned in this Section, see Section 16.

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapor. H250 Catches fire spontaneously if exposed to air. H260 In contact with water releases flammable gases which may ignite spontaneously. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H336 May cause drowsiness or dizziness. H361 Suspected of damaging fertility or the unborn child. H373 May cause damage to organs (Central nervous system) through prolonged or repeated exposure if inhaled.

Prevention

P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P231 + P232 Handle under inert gas. Protect from moisture. P260 Do not breathe mist or vapors. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302 + P334 IF ON SKIN: Immerse in cool water/ wrap in wet bandages. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P335 + P334 Brush off loose particles from skin. Immerse in cool water/ wrap in wet bandages. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

Other hazards

Reacts violently with water

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