Phenylhydrazine

Sigma-Aldrich

Revision date : 2017-10-03

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GHS06 GHS07 GHS08 GHS09
Health risk rating 5
Safety risk rating 1
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

100-63-0

Name of the chemical

Phenylhydrazin

Concentration

N/A

EC/CAS

202-873-5

Name of the chemical

Phenylhydrazin

Concentration

N/A

General Information

Revision date

2017-10-03

Product name

Phenylhydrazine

CAS No.

100-63-0

Emergency telephone

+1-703-527-3887 (CHEMTREC

Icons in SDS

Company Information

company name

Sigma-Aldrich

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H227, H301, H301+H311+H331, H311, H315, H317, H319, H331, H341, H350, H400

Hazard statements

Code

Statements

H227

Combustible liquid

Section 2

OSHA HCS Classification

Flammable liquids (Category 4), H227 Acute toxicity, Oral (Category 3), H301 Acute toxicity, Inhalation (Category 3), H331 Acute toxicity, Dermal (Category 3), H311 Skin irritation (Category 2), H315 Eye irritation (Category 2A), H319 Skin sensitisation (Category 1), H317 Germ cell mutagenicity (Category 2), H341 Carcinogenicity (Category 1B), H350 Acute aquatic toxicity (Category 1), H400 For the full text of the H-Statements mentioned in this Section, see Section 16.

Signal word

Danger

Hazard statements

H227 Combustible liquid. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H341 Suspected of causing genetic defects. H350 May cause cancer. H400 Very toxic to aquatic life.

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P322 Specific measures (see supplemental first aid instructions on this label). P330 Rinse mouth. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P361 Remove/Take off immediately all contaminated clothing. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. P391 Collect spillage. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Other hazards

none

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