Phenyllithium (20% solution in dibutylether)

Hazard statements (CLP)

H226, H316, H319, H333, H335, H340, H350, H360, H373, H402, H411

Code

Statements

H226

Flammable liquid and vapour

2.1 Classification of the substance or mixture

Flammable Liquids (Category C), H226 Acute toxicity, Inhalation (Category E), H333 Skin irritation (Category B), H316 Eye irritation (Category A), H319 Germ cell mutagenicity (Category A), H340 Carcinogenicity (Category A), H350 Toxic to Reproduction (Category A), H360 Acute toxicity (Category E), Respiratory system, H335 Specific Target Organ Toxicity (Category B), H373 Aquatic toxicity (Acute or Chronic) (Category B), H411 For the full text of the H-Statements mentioned in this Section, see Section 16.

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapor. H316 Causes mild skin irritation. H319 Causes serious eye irritation. H333 May be harmful if inhaled. H335 May cause respiratory irritation. H340 May cause genetic defects. H350 May cause cancer. H360 May damage fertility or the unborn child. H373 May cause damage to organs through prolonged or repeated exposure. H402 Harmful to aquatic life. H411 Toxic to aquatic life with long lasting effects.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Other hazards

Reacts violently with water.