General Information
Version
7.3
Revision date
2023-12-30
Product name
Methyl formate
CAS No.
107-31-3
REACH No
is
Emergency telephone
+65 3158 1349
Icons in SDS
Company Information
company name
Sigma-Aldrich Pte Ltd
e-mail address of the competent person responsible for the Safety Data Sheet
TechnicalService@merckgroup.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H224, H301, H301+H311+H331, H311, H319, H331, H335, H370
Hazard statements
Code
Statements
H224
Extremely flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Flammable liquids, (Category 1) H224: Extremely flammable liquid and vapor. Acute toxicity, (Category 3) H301: Toxic if swallowed. Acute toxicity, (Category 3) H331: Toxic if inhaled. Acute toxicity, (Category 3) H311: Toxic in contact with skin. Eye irritation, (Category 2) H319: Causes serious eye irritation. Specific target organ toxicity - H370: Causes damage to organs. single exposure, (Category 1) Specific target organ toxicity - H335: May cause respiratory irritation. single exposure, (Category 3), Respiratory system
2.2 Label elements
Labelling
Signal word
Danger Danger
Hazard statements
H224 Extremely flammable liquid and vapor. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H370 Causes damage to organs. Reduced Labeling (<= 125 ml) H224 Extremely flammable liquid and vapor. H370 Causes damage to organs. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
Supplemental label elements
none none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.