Magnesium bis(diisopropyl)amide solution

Sigma-Aldrich

Revision date : 2016-05-23

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GHS02 GHS05 GHS06 GHS07 GHS08
Health risk rating 4
Safety risk rating 3
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

109-99-9

Name of the chemical

Tetrahydrofuran (618/2012)

Concentration

N/A

EC/CAS

203-726-8

Name of the chemical

Tetrahydrofuran (618/2012)

Concentration

N/A

General Information

Revision date

2016-05-23

Product name

Magnesium bis(diisopropyl)amide solution

CAS No.

23293-23-4

Emergency telephone

+1-703-527-3887 (CHEMTREC

Icons in SDS

Company Information

company name

Sigma-Aldrich

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H261, H302, H304, H314, H318, H331, H335, H341, H351, H402, H412

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

OSHA HCS Classification

Flammable liquids (Category 2), H225 Substances and mixtures, which in contact with water, emit flammable gases (Category 2), H261 Acute toxicity, Oral (Category 4), H302 Acute toxicity, Inhalation (Category 3), H331 Skin corrosion (Category 1A), H314 Serious eye damage (Category 1), H318 Germ cell mutagenicity (Category 2), H341 Carcinogenicity (Category 2), H351 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335

Aspiration hazard

Category 1), H304 Acute aquatic toxicity (Category 3), H402 Chronic aquatic toxicity (Category 3), H412 For the full text of the H-Statements mentioned in this Section, see Section 16.

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour. H261 In contact with water releases flammable gases. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H331 Toxic if inhaled. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H351 Suspected of causing cancer. H412 Harmful to aquatic life with long lasting effects.

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P223 Do not allow contact with water. P231 + P232 Handle under inert gas. Protect from moisture. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P335 + P334 Brush off loose particles from skin. Immerse in cool water/ wrap in wet bandages. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P402 + P404 Store in a dry place. Store in a closed container. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Other hazards

Reacts violently with water., May form explosive peroxides.

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