Luperox TBH70X, tert-Butyl hydroperoxide solution

Sigma-Aldrich

Revision date : 2018-02-07

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GHS02 GHS05 GHS06 GHS07 GHS08 GHS09
Health risk rating 4
Safety risk rating 4
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

75-91-2

Name of the chemical

tert-Butylhydroperoxid (2016/1179)

Concentration

N/A

EC/CAS

200-915-7

Name of the chemical

tert-Butylhydroperoxid (2016/1179)

Concentration

N/A

General Information

Revision date

2018-02-07

Product name

Luperox TBH70X, tert-Butyl hydroperoxide solution

CAS No.

75-91-2

Emergency telephone

+1-703-527-3887 (CHEMTREC

Icons in SDS

Company Information

company name

Sigma-Aldrich

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H242, H302, H311, H311+H331, H314, H317, H318, H331, H341, H401, H411

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

OSHA HCS Classification

Flammable liquids (Category 3), H226 Organic peroxides (Type F), H242 Acute toxicity, Oral (Category 4), H302 Acute toxicity, Inhalation (Category 3), H331 Acute toxicity, Dermal (Category 3), H311 Skin corrosion (Category 1C), H314 Serious eye damage (Category 1), H318 Skin sensitisation (Category 1), H317 Germ cell mutagenicity (Category 2), H341 Acute aquatic toxicity (Category 2), H401 Chronic aquatic toxicity (Category 2), H411 For the full text of the H-Statements mentioned in this Section, see Section 16.

Signal word

Danger Danger

Hazard statements

H226 Flammable liquid and vapour. H242 Heating may cause a fire. H302 Harmful if swallowed. H311 + H331 Toxic in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H341 Suspected of causing genetic defects. H411 Toxic to aquatic life with long lasting effects. H226 Flammable liquid and vapour. H242 Heating may cause a fire. H302 Harmful if swallowed. H311 + H331 Toxic in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H341 Suspected of causing genetic defects. H411 Toxic to aquatic life with long lasting effects.

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P220 Keep/Store away from clothing/ combustible materials. P233 Keep container tightly closed. P234 Keep only in original container. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P235 Keep cool. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor. P322 Specific measures (see supplemental first aid instructions on this label). P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P361 Remove/Take off immediately all contaminated clothing. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. P391 Collect spillage. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P410 Protect from sunlight. P420 Store away from other materials. P501 Dispose of contents/ container to an approved waste disposal plant. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P220 Keep/Store away from clothing/ combustible materials. P233 Keep container tightly closed. P234 Keep only in original container. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P281 Use personal protective equipment as required. P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. P391 Collect spillage. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P410 Protect from sunlight. P411 + P235 Store at temperatures not exceeding .? °C/ .? °F. Keep cool. P420 Store away from other materials. P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Other hazards

none

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