Picric acid

Sigma-Aldrich Inc

Revision date : 2025-11-28

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GHS02 GHS06
Health risk rating 3
Safety risk rating 4
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

88-89-1

Name of the chemical

Picric acid

Concentration

>= 60 - <= 80

General Information

Version

6.15

Revision date

2025-11-28

Product name

Picric acid

CAS No.

88-89-1

1.2.1 Relevant identified uses

Laboratory chemicals, Synthesis of substances

1.2.2. Uses advised against

The product is being supplied under the TSCA R&D Exemption

Emergency telephone

800-424-9300, +1-703- 527-3887

Icons in SDS

GHS02 GHS06 M004 M010 M011 M017

Company Information

company name

Sigma-Aldrich Inc

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H206, H302, H311+H331

Hazard statements

Code

Statements

H206

Fire, blast or projection hazard; increased risk of explosion if desensitising agent is reduced

Section 2

SECTION 2: Hazards identification

Other hazards

Explosive with or without contact with air

Signal word

Danger

Hazard statements

H206 Fire, blast or projection hazard; increased risk of explosion if desensitising agent is reduced. H302 Harmful if swallowed. H311 + H331 Toxic in contact with skin or if inhaled.

Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P212 Avoid heating under confinement or reduction of the desensitising agent. P230 Keep wetted with water. P233 Keep container tightly closed. P261 Avoid breathing dust. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P302 + P352 + P312 IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/ doctor if you feel unwell. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P361 + P364 Take off immediately all contaminated clothing and wash it before reuse. P370 + P380 + P375 In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.

Storage

P401 Store in accordance with local regulations. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

2.1 Classification of the substance or mixture

(29 CFR 1910.1200) Hazards for the product as supplied Desensitised explosives : Category 1 Acute toxicity (Oral) : Category 4 Acute toxicity : Category 3 (Inhalation) Acute toxicity (Dermal) : Category 3 Other hazards Explosive with or without contact with air.

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