Note: Ingredients listed on restricted chemical lists
EC/CAS
203-726-8/109-99-9
Name of the chemical
Tetrahydrofuran (618/2012)
Concentration
>=70-<90
General Information
Version
6.5
Revision date
2023-04-15
Product name
Phenylethynylmagnesium bromide solution
CAS No.
6738-06-3
REACH No
This
Emergency telephone
800-424-9300 CHEMTREC (USA) +1-703- 527-3887 CHEMTREC (International) 24
Icons in SDS
Company Information
company name
Sigma-Aldrich Inc
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H250, H261, H314, H318, H335, H336, H351
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification
2.2 Label elements
Labelling
Signal word
Danger Danger
Hazard statements
H225 Highly flammable liquid and vapor. H250 Catches fire spontaneously if exposed to air. H261 In contact with water releases flammable gas. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H250 Catches fire spontaneously if exposed to air. H351 Suspected of causing cancer. H314 Causes severe skin burns and eye damage.
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
Supplemental label elements
EUH014 Reacts violently with water. EUH019 May form explosive peroxides. Reduced Labeling (<= 125 ml) EUH014 Reacts violently with water. EUH019 May form explosive peroxides.
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Reacts violently with water.