Phenol solution, 1.0 M in DCM

Sigma-Aldrich Inc

Revision date : 2025-06-26

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GHS08 GHS05 GHS07
Health risk rating 4
Safety risk rating 1
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

75-09-2

Name of the chemical

Methylene chloride

Concentration

>=80-<=100

EC/CAS

108-95-2

Name of the chemical

Phenol

Concentration

>=5-<=10

General Information

Version

6.8

Revision date

2025-06-26

Product name

Phenol solution, 1.0 M in DCM

1.2.1 Relevant identified uses

Laboratory chemicals, Synthesis of substances

1.2.2. Uses advised against

After February 3, 2025, this chemical substance (as defined in

Emergency telephone

800-424-9300, +1-703- 527-3887

Icons in SDS

GHS05 GHS07 GHS08

Company Information

company name

Sigma-Aldrich Inc

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H302+H312, H314, H336, H341, H351, H373, H412

Hazard statements

Code

Statements

H302+H312

Harmful if swallowed or in contact with skin

Section 2

SECTION 2: Hazards identification

Long term hazards

Category 3 aquatic hazard

Other hazards

None known

Signal word

Danger

Hazard statements

H302 + H312 Harmful if swallowed or in contact with skin. H314 Causes severe skin burns and eye damage. H336 May cause drowsiness or dizziness. H341 Suspected of causing genetic defects. H351 Suspected of causing cancer. H373 May cause damage to organs (Nervous system, Kidney, Liver, Skin) through prolonged or repeated exposure. H412 Harmful to aquatic life with long lasting effects.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe mist or vapours. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P363 Wash contaminated clothing before reuse.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

2.1 Classification of the substance or mixture

(29 CFR 1910.1200) Acute toxicity (Oral) : Category 4 Acute toxicity (Dermal) : Category 4 Skin corrosion : Category 1B Serious eye damage : Category 1 Germ cell mutagenicity : Category 2 Carcinogenicity : Category 2 Specific target organ : Category 3 (Central nervous system) toxicity - single exposure Specific target organ : Category 2 (Nervous system, Kidney, Liver, Skin) toxicity - repeated exposure Short-term (acute) : Category 3 aquatic hazard Long-term (chronic) : Category 3 aquatic hazard Other hazards

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