Hexylzinc bromide solution

Sigma-Aldrich Inc

Revision date : 2023-11-27

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GHS07 GHS08 GHS02
Health risk rating 4
Safety risk rating 3
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

109-99-9

Name of the chemical

Tetrahydrofuran (618/2012)

Concentration

>=90-< 5-53 100%

General Information

Version

8.7

Revision date

2023-11-27

Product name

Hexylzinc bromide solution

CAS No.

124397-96-2

1.2.1 Relevant identified uses

Laboratory chemicals, Synthesis of substances

Emergency telephone

800-424-9300, +1-703- 527-3887

Icons in SDS

GHS02 GHS07 GHS08

Company Information

company name

Sigma-Aldrich Inc

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H261, H302, H319, H335, H336, H351

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

GHS Classification in Accordance with 29 CFR 1910 (OSHA HCS): Classification of the substance or mixture

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapor. H261 In contact with water releases flammable gas. H302 Harmful if swallowed. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer.

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P223 Do not allow contact with water. P231 + P232 Handle under inert gas. Protect from moisture. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P335 + P334 Brush off loose particles from skin. Immerse in cool water/ wrap in wet bandages. P337 + P313 If eye irritation persists: Get medical advice/ attention. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P402 + P404 Store in a dry place. Store in a closed container. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Other hazards

In use may form flammable/explosive vapor-air mixture., May form explosive peroxides.

2.1 Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) Flammable liquids (Category 2), H225 Chemicals which, in contact with water, emit flammable gases (Category 2), H261 Acute toxicity, Oral (Category 4), H302 Eye irritation (Category 2A), H319 Carcinogenicity (Category 2), H351 Specific target organ toxicity - single exposure (Category 3), Respiratory system, Central nervous system, H335, H336 For the full text of the H-Statements mentioned in this Section, see Section 16.

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