EPA Appendix IX Volatiles Calibration Mix

Sigma-Aldrich Inc

Revision date : 2023-04-16

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GHS02 GHS06 GHS07 GHS08 GHS09
Health risk rating 5
Safety risk rating 3
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

200-659-6/67-56-1

Name of the chemical

Methanol

Concentration

>=90-< 100% 603-001-

EC/CAS

203-457-6/107-05-1

Name of the chemical

3-Chlorpropen

Concentration

>=0,1-< 0,25% 602-029-

EC/CAS

202-597-5/97-63-2

Name of the chemical

methacrylic acid, ethyl ester

Concentration

>=0,1-<1

EC/CAS

203-466-5/107-13-1

Name of the chemical

Acrylonitrile

Concentration

>=0,1-< 0,25%

EC/CAS

201-297-1/80-62-6

Name of the chemical

methacrylic acid, methyl ester

Concentration

>=0,1-<1

EC/CAS

204-661-8/123-91-1

Name of the chemical

1,4-Dioxane

Concentration

>=0,1-<1

EC/CAS

201-167-4/79-01-6

Name of the chemical

Trichloroethylene

Concentration

>=0,1-< 0,25%

EC/CAS

203-444-5/106-93-4

Name of the chemical

1,2-Dibromethan

Concentration

>=0,1-< 0,25%

EC/CAS

202-486-1/96-18-4

Name of the chemical

1,2,3-trichloropropane

Concentration

>=0,1-< 0,25% 602-062-

EC/CAS

204-825-9/127-18-4

Name of the chemical

Tetrachloroethylene

Concentration

>=0,1-< 0,25%

EC/CAS

200-864-0/75-35-4

Name of the chemical

1,1-Dichlorethen

Concentration

0,25%

EC/CAS

200-663-8/67-66-3

Name of the chemical

Chloroform

Concentration

>=0,1-<1

EC/CAS

211-135-1/630-20-6

Name of the chemical

1,1,1,2-Tetrachloroethane

Concentration

>=0,1-< 0,25%

EC/CAS

201-152-2/78-87-5

Name of the chemical

1,2-Dichlorpropan (2016/1179)

Concentration

>=0,1-<1

EC/CAS

202-479-3/96-12-8

Name of the chemical

1,2-Dibrom-3-chlorpropan

Concentration

>=0,1-< 0,25%

EC/CAS

203-458-1/107-06-2

Name of the chemical

1,2-Dichloroethane; ethylene dichloride

Concentration

>=0,1-<1

EC/CAS

202-851-5/100-42-5

Name of the chemical

Styrene ( Vinyl benzene )

Concentration

>=0,1-< 0,25%

EC/CAS

201-197-8/79-34-5

Name of the chemical

1,1,2,2-Tetrachloroethane

Concentration

>=0,1-< 0,25%

EC/CAS

201-166-9/79-00-5

Name of the chemical

1,1,2-Trichloroethane

Concentration

>=0,1-< 0,25%

EC/CAS

202-425-9/95-50-1

Name of the chemical

1,2-dichlorobenzene

Concentration

>=0,1-< 0,25%

EC/CAS

203-400-5/106-46-7

Name of the chemical

1,4-Dichlorbenzol

Concentration

>=0,1-< 0,25%

EC/CAS

200-666-4/67-72-1

Name of the chemical

Hexachloroethane

Concentration

>=0,1-< 0,25%

EC/CAS

202-049-5/91-20-3

Name of the chemical

Naphthalene,3

Concentration

>=0,1-< 0,25%

EC/CAS

203-625-9/108-88-3

Name of the chemical

Toluene

Concentration

>=0,1-< 0,25%

EC/CAS

200-838-9/75-09-2

Name of the chemical

Methylene chloride

Concentration

>=0,1-<1

EC/CAS

200-925-1/76-01-7

Name of the chemical

Pentachloroethane

Concentration

>=0,2-< 0,25%

EC/CAS

204-817-5/126-98-7

Name of the chemical

methacrylonitrile

Concentration

>=0,2-<1

EC/CAS

200-843-6/75-15-0

Name of the chemical

Kohlendisulfid

Concentration

>=0,2-<1

EC/CAS

200-262-8/56-23-5

Name of the chemical

Carbon tetrachloride

Concentration

>=0,2-< 0,25%

General Information

Version

7.11

Revision date

2023-04-16

Product name

EPA Appendix IX Volatiles Calibration Mix

REACH No

This

Emergency telephone

800-424-9300 CHEMTREC (USA) +1-703- 527-3887 CHEMTREC (International) 24

Icons in SDS

GHS02 GHS06 GHS08 GHS09

Company Information

company name

Sigma-Aldrich Inc

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H301, H301+H311+H331, H311, H317, H331, H340, H350, H370, H373, H411, H420

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

2.1 Classification of the substance or mixture

Classification

2.2 Label elements

Labelling

Signal word

Danger Danger

Hazard statements

H225 Highly flammable liquid and vapor. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H317 May cause an allergic skin reaction. H340 May cause genetic defects. H350 May cause cancer. H370 Causes damage to organs (Eyes, Central nervous system). H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. H420 Harms public health and the environment by destroying ozone in the upper atmosphere. Restricted to professional users. For use in industrial installations only. Reduced Labeling (<= 125 ml) H317 May cause an allergic skin reaction. H340 May cause genetic defects. H350 May cause cancer. H370 Causes damage to organs. H420 Harms public health and the environment by destroying ozone in the upper atmosphere. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P502 Refer to manufacturer or supplier for information on recovery or recycling. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P502 Refer to manufacturer or supplier for information on recovery or recycling.

Supplemental label elements

none none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

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