Phosphorus, white

Sigma-Aldrich Handels GmbH

Revision date : 2024-01-16

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GHS05 GHS09 GHS06 GHS02
Health risk rating 2
Safety risk rating 4
Environmental risk rating 4

General Information

Version

8.6

Revision date

2024-01-16

Product name

Phosphorus, white

CAS No.

12185-10-3

REACH No

A

Emergency telephone

+43 1 364 92 37

Icons in SDS

GHS02 GHS05 GHS06 GHS09

Company Information

company name

Sigma-Aldrich Handels GmbH

e-mail address of the competent person responsible for the Safety Data Sheet

technischerservice@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H250, H300+H330, H314, H400

Hazard statements

Code

Statements

H250

Catches fire spontaneously if exposed to air

Section 2

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Pyrophoric solids, (Category 1) H250: Catches fire spontaneously if exposed to air. Acute toxicity, (Category 2) H300: Fatal if swallowed. Acute toxicity, (Category 2) H330: Fatal if inhaled. Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1A) damage. Serious eye damage, (Category H318: Causes serious eye damage. 1) Short-term (acute) aquatic H400: Very toxic to aquatic life. hazard, (Category 1)

Signal word

Danger Danger

Hazard statements

H250 Catches fire spontaneously if exposed to air. H300 + H330 Fatal if swallowed or if inhaled. H314 Causes severe skin burns and eye damage. H400 Very toxic to aquatic life. H250 Catches fire spontaneously if exposed to air. H314 Causes severe skin burns and eye damage. H300 + H330 Fatal if swallowed or if inhaled.

Precautionary statements

P260 Do not breathe dusts or mists. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P260 Do not breathe dusts or mists. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

Supplemental label elements

none Reduced Labeling (<= 125 ml) none

Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

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