General Information
Version
8.6
Revision date
2024-01-16
Product name
Phosphorus, white
CAS No.
12185-10-3
REACH No
A
Emergency telephone
+43 1 364 92 37
Icons in SDS
Company Information
company name
Sigma-Aldrich Handels GmbH
e-mail address of the competent person responsible for the Safety Data Sheet
technischerservice@merckgroup.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H250, H300+H330, H314, H400
Hazard statements
Code
Statements
H250
Catches fire spontaneously if exposed to air
Section 2
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Pyrophoric solids, (Category 1) H250: Catches fire spontaneously if exposed to air. Acute toxicity, (Category 2) H300: Fatal if swallowed. Acute toxicity, (Category 2) H330: Fatal if inhaled. Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1A) damage. Serious eye damage, (Category H318: Causes serious eye damage. 1) Short-term (acute) aquatic H400: Very toxic to aquatic life. hazard, (Category 1)
Signal word
Danger Danger
Hazard statements
H250 Catches fire spontaneously if exposed to air. H300 + H330 Fatal if swallowed or if inhaled. H314 Causes severe skin burns and eye damage. H400 Very toxic to aquatic life. H250 Catches fire spontaneously if exposed to air. H314 Causes severe skin burns and eye damage. H300 + H330 Fatal if swallowed or if inhaled.
Precautionary statements
P260 Do not breathe dusts or mists. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P260 Do not breathe dusts or mists. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
Supplemental label elements
none Reduced Labeling (<= 125 ml) none
Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.