General Information
Revision date
2021-05-25
Product name
(Trimethylsilyl)diazomethane solution
REACH No
This
Emergency telephone
0800 181 7059 (CHEMTREC Deutschland
Icons in SDS
Company Information
company name
Sigma-Aldrich Chemie GmbH
e-mail address of the competent person responsible for the Safety Data Sheet
technischerservice@merckgroup.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H302, H330, H336, H350, H370
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
CLP CLASSIFICATION
Flammable liquids (Category 2), H225 Acute toxicity, Oral (Category 4), H302 Acute toxicity, Inhalation (Category 2), H330 Carcinogenicity (Category 1B), H350 Specific target organ toxicity - single exposure, Inhalation (Category 1), Lungs, H370 Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336 For the full text of the H-Statements mentioned in this Section, see Section 16.
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Signal word
Danger Danger
Hazard statements
H225 Highly flammable liquid and vapor. H302 Harmful if swallowed. H330 Fatal if inhaled. H336 May cause drowsiness or dizziness. H350 May cause cancer. H370 Causes damage to organs (Lungs) if inhaled. H330 Fatal if inhaled. H350 May cause cancer. H370 Causes damage to organs if inhaled.
Precautionary statements
P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P202 Do not handle until all safety precautions have been read and understood. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
Supplemental label elements
EUH019 May form explosive peroxides. EUH066 Repeated exposure may cause skin dryness or cracking. Reduced Labeling (<= 125 ml) EUH019 May form explosive peroxides. EUH066 Repeated exposure may cause skin dryness or cracking.
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Preliminary data indicates this product may be highly toxic or fatal if inhaled., Inhalation may provoke the following symptoms:, pulmonary edema, Symptoms may be delayed for hours after exposure.
