Tetramethylammonium hydroxide solution

Sigma-Aldrich Chemie GmbH

Revision date : 2024-06-28

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GHS06 GHS08 GHS05
Health risk rating 4
Safety risk rating 1
Environmental risk rating 3

General Information

Version

7.4

Revision date

2024-06-28

Product name

Tetramethylammonium hydroxide solution

REACH No

This

Emergency telephone

+49 (0)696 43508409

Icons in SDS

GHS05 GHS06 GHS08

Company Information

company name

Sigma-Aldrich Chemie GmbH

e-mail address of the competent person responsible for the Safety Data Sheet

technischerservice@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H301, H301+H311, H311, H314, H318, H371, H373, H412

Hazard statements

Code

Statements

H301

Toxic if swallowed

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture Acute toxicity, (Category 3) H301: Toxic if swallowed Acute toxicity, (Category 3) H311: Toxic in contact with skin Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1B) damage Serious eye damage, (Category H318: Causes serious eye damage. 1) Specific target organ toxicity - H371: May cause damage to organs. single exposure, (Category 2), Central nervous system Specific target organ toxicity H373: May cause damage to organs repeated exposure, (Category 2), through prolonged or repeated exposure in Liver, thymus contact with skin Long-term (chronic) aquatic H412: Harmful to aquatic life with long hazard, (Category 3) lasting effects.

Signal word

Danger Danger

Hazard statements

H301 + H311 Toxic if swallowed or in contact with skin. H314 Causes severe skin burns and eye damage. H371 May cause damage to organs (Central nervous system). H373 May cause damage to organs (Liver, thymus) through prolonged or repeated exposure in contact with skin. H412 Harmful to aquatic life with long lasting effects. H314 Causes severe skin burns and eye damage. H412 Harmful to aquatic life with long lasting effects. H301 + H311 Toxic if swallowed or in contact with skin.

Precautionary statements

P260 Do not breathe mist or vapors. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental label elements

none Reduced Labeling (<= 125 ml) none

Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Acute toxicity, (Category 3) H301: Toxic if swallowed. Acute toxicity, (Category 3) H311: Toxic in contact with skin. Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1B) damage. Serious eye damage, (Category H318: Causes serious eye damage. 1) Specific target organ toxicity - H371: May cause damage to organs. single exposure, (Category 2), Central nervous system Specific target organ toxicity - H373: May cause damage to organs repeated exposure, (Category 2), through prolonged or repeated exposure in Liver, thymus contact with skin. Long-term (chronic) aquatic H412: Harmful to aquatic life with long hazard, (Category 3) lasting effects.

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