tert-Butyl hydroperoxide solution tert-Butyl hydroperoxide solution

Sigma-Aldrich Chemie GmbH

Revision date : 2022-06-14

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GHS09 GHS06 GHS02 GHS08
Health risk rating 5
Safety risk rating 4
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

200-915-7/75-91-2

Name of the chemical

tert-Butylhydroperoxid (2016/1179)

Concentration

>=50-< 80%

EC/CAS

203-733-6/110-05-4

Name of the chemical

Di-tert-butylperoxid (618/2012)

Concentration

>=10-<20

EC/CAS

231-791-2/7732-18-5

Name of the chemical

Water, distilled, conductivity or of similar purity H2O

Concentration

>7-<10%

General Information

Version

6.6

Revision date

2022-06-14

Product name

tert-Butyl hydroperoxide solution tert-Butyl hydroperoxide solution

REACH No

This

Emergency telephone

+49 (0)696 43508409

Icons in SDS

GHS02 GHS06 GHS08 GHS09

Company Information

company name

Sigma-Aldrich Chemie GmbH

e-mail address of the competent person responsible for the Safety Data Sheet

technischerservice@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H242, H302, H311, H314, H317, H330, H335, H341, H411

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger Danger

Hazard statements

H226 Flammable liquid and vapor. H242 Heating may cause a fire. H302 Harmful if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H330 Fatal if inhaled. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H411 Toxic to aquatic life with long lasting effects. H330 Fatal if inhaled. H311 Toxic in contact with skin. H317 May cause an allergic skin reaction. H341 Suspected of causing genetic defects. H314 Causes severe skin burns and eye damage.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental label elements

none Reduced Labeling (<= 125 ml) none

Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher

2.1 Classification of the substance or mixture

Flammable liquids (Category 3), H226 Organic peroxides (Type C), H242 Acute toxicity, Oral (Category 4), H302 Acute toxicity, Inhalation (Category 2), H330 Acute toxicity, Dermal (Category 3), H311 Skin corrosion (Sub-category 1C), H314 Serious eye damage (Category 1), H318 Skin sensitization (Category 1), H317 Germ cell mutagenicity (Category 2), H341 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Long-term (chronic) aquatic hazard (Category 2), H411 For the full text of the H-Statements mentioned in this Section, see Section 16. 2.2 Label elements

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