Sodium tert-pentoxide solution

Sigma-Aldrich Chemie GmbH

Revision date : 2024-03-01

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GHS02 GHS05 GHS08
Health risk rating 4
Safety risk rating 5
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

203-625-9/108-88-3

Name of the chemical

Toluene

Concentration

>=50-<70

EC/CAS

215-185-5/1310-73-2

Name of the chemical

sodium hydroxide

Concentration

>=2-<3%

General Information

Version

7.6

Revision date

2024-03-01

Product name

Sodium tert-pentoxide solution

REACH No

This

Emergency telephone

+49 (0)696 43508409

Icons in SDS

GHS02 GHS05 GHS08

Company Information

company name

Sigma-Aldrich Chemie GmbH

e-mail address of the competent person responsible for the Safety Data Sheet

technischerservice@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H261, H290, H304, H314, H318, H332, H335, H336, H361d, H373, H412

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Flammable liquids, (Category 2) H225: Highly flammable liquid and vapor. Substances and mixtures which H261: In contact with water releases in contact with water emit flammable gas. flammable gases, (Category 2) Corrosive to Metals, (Category 1) H290: May be corrosive to metals. Acute toxicity, (Category 4) H332: Harmful if inhaled. Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1B) damage. Serious eye damage, (Category H318: Causes serious eye damage. 1) Reproductive toxicity, (Category H361d: Suspected of damaging the unborn 2) child. Specific target organ toxicity - H335: May cause respiratory irritation. single exposure, (Category 3), Respiratory system Specific target organ toxicity - H336: May cause drowsiness or dizziness. single exposure, (Category 3), Central nervous system Specific target organ toxicity - H373: May cause damage to organs repeated exposure, (Category 2), through prolonged or repeated exposure. Central nervous system Aspiration hazard, (Category 1) H304: May be fatal if swallowed and enters airways. Long-term (chronic) aquatic H412: Harmful to aquatic life with long hazard, (Category 3) lasting effects.

2.2 Label elements

Labelling

Signal word

Danger Danger

Hazard statements

H225 Highly flammable liquid and vapor. H261 In contact with water releases flammable gas. H290 May be corrosive to metals. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H361d Suspected of damaging the unborn child. H373 May cause damage to organs (Central nervous system) through prolonged or repeated exposure. H412 Harmful to aquatic life with long lasting effects. Reduced Labeling (<= 125 ml) H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H412 Harmful to aquatic life with long lasting effects. H361d Suspected of damaging the unborn child.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental label elements

none none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Reacts violently with water.

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