General Information
Version
8.6
Revision date
2024-01-16
Product name
Phosphorus, white
CAS No.
12185-10-3
REACH No
is
Emergency telephone
+49 (0)696 43508409
Icons in SDS
Company Information
company name
Sigma-Aldrich Chemie GmbH
e-mail address of the competent person responsible for the Safety Data Sheet
technischerservice@merckgroup.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H250, H300, H300+H330, H314, H318, H330, H400
Hazard statements
Code
Statements
H250
Catches fire spontaneously if exposed to air
Section 2
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Pyrophoric solids, (Category 1) H250 Catches fire spontaneously if exposed to air Acute toxicity, (Category 2) H300: Fatal if swallowed. Acute toxicity, (Category 2) H330 Fatal if inhaled. Skin corrosion, (Sub-category H314 Causes severe skin burns and eye 1A) damage. Serious eye damage, (Category H318 Causes serious eye damage. 1) Short-term (acute) aquatic H400: Very toxic to aquatic life. hazard, (Category 1)
2.2 Label elements
Labelling
Signal word
Danger Danger
Hazard statements
H250 Catches fire spontaneously if exposed to air. H300 + H330 Fatal if swallowed or if inhaled. H314 Causes severe skin burns and eye damage. H400 Very toxic to aquatic life. Reduced Labeling (<= 125 ml) H250 Catches fire spontaneously if exposed to air. H314 Causes severe skin burns and eye damage. H300 + H330 Fatal if swallowed or if inhaled.
Precautionary statements
P260 Do not breathe dusts or mists. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P260 Do not breathe dusts or mists. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
Supplemental label elements
none none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.