n-Butyllithium solution

Sigma-Aldrich Chemie GmbH

Revision date : 2022-06-20

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GHS02 GHS05 GHS07 GHS08 GHS09
Health risk rating 3
Safety risk rating 4
Environmental risk rating 5

General Information

Revision date

2022-06-20

Product name

n-Butyllithium solution

Emergency telephone

0800 181 7059 (CHEMTREC Deutschland

Icons in SDS

GHS02 GHS07 GHS09

Company Information

company name

Sigma-Aldrich Chemie GmbH

e-mail address of the competent person responsible for the Safety Data Sheet

technischerservice@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H260, H304, H314, H318, H336, H400, H410

Hazard statements

Code

Statements

H260

In contact with water releases flammable gases which may ignite spontaneously

Section 2

2.1 Classification of the substance or mixture

Classification

Aspiration hazard

Category 1), H304 Short-term (acute) aquatic hazard (Category 1), H400 Long-term (chronic) aquatic hazard (Category 1), H410 For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

Labelling

Signal word

Danger Danger

Hazard statements

H260 In contact with water releases flammable gases which may ignite spontaneously. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H336 May cause drowsiness or dizziness. H410 Very toxic to aquatic life with long lasting effects. H314 Causes severe skin burns and eye damage. H304 May be fatal if swallowed and enters airways.

Precautionary statements

P231 + P232 Handle and store contents under inert gas. Protect from moisture. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 + P331 IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 + P331 IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor.

Supplemental label elements

EUH014 Reacts violently with water. Reduced Labeling (<= 125 ml) EUH014 Reacts violently with water.

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

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