Note: Ingredients listed on restricted chemical lists
EC/CAS
200-663-8/67-66-3
Name of the chemical
Chloroform
Concentration
>=50-<70
General Information
Version
7.4
Revision date
2025-10-14
Product name
HYDRANAL -Working Medium K
Emergency telephone
+49 (0)696 43508409
Icons in SDS
Company Information
company name
Sigma-Aldrich Chemie GmbH
e-mail address of the competent person responsible for the Safety Data Sheet
technischerservice@merckgroup.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H290, H300, H300+H310+H330, H310, H315, H318, H330, H336, H351, H361d, H372, H411
Hazard statements
Code
Statements
H290
May be corrosive to metals
Section 2
SECTION 2: Hazards identification
Regulation (EC) No. 1272/2008 Classification of the substance or mixture Corrosive to metals, (Category 1) H290: May be corrosive to metals Acute toxicity, (Category 2) H300: Fatal if swallowed Acute toxicity, (Category 1) H330: Fatal if inhaled Acute toxicity, (Category 1) H310: Fatal in contact with skin Skin irritation, (Category 2) H315: Causes skin irritation Serious eye damage, (Category H318: Causes serious eye damage Carcinogenicity, (Category 2) H351: Suspected of causing cancer Reproductive toxicity, (Category H361d: Suspected of damaging the unborn child Specific target organ toxicity - H336: May cause drowsiness or dizziness single exposure, (Category 3), Central nervous system Specific target organ toxicity - H372: Causes damage to organs through repeated exposure, (Category 1), prolonged or repeated exposure if Liver, Kidney swallowed Long-term (chronic) aquatic H411: Toxic to aquatic life with long lasting hazard, (Category 2) effects
Signal word
Danger Danger
Hazard statements
H290 May be corrosive to metals. H300 + H310 + H330 Fatal if swallowed, in contact with skin or if inhaled. H315 Causes skin irritation. H318 Causes serious eye damage. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H361d Suspected of damaging the unborn child. H372 Causes damage to organs (Liver, Kidney) through prolonged or repeated exposure if swallowed. H411 Toxic to aquatic life with long lasting effects. For use in industrial installations only. Reduced Labelling (<= 125 ml) H351 Suspected of causing cancer. H372 Causes damage to organs through prolonged or repeated exposure if swallowed. H318 Causes serious eye damage. H361d Suspected of damaging the unborn child. H300 + H310 + H330 Fatal if swallowed, in contact with skin or if inhaled.
Precautionary statements
P264 Wash skin thoroughly after handling. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P302 + P352 + P310 IF ON SKIN: Wash with plenty of water. Immediately call a POISON CENTER/ doctor. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P302 + P352 + P310 IF ON SKIN: Wash with plenty of water. Immediately call a POISON CENTER/ doctor. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Supplemental label elements
none none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
2.1 Classification of the substance or mixture
Corrosive to metals, (Category 1) H290: May be corrosive to metals. Acute toxicity, (Category 2) H300: Fatal if swallowed. Acute toxicity, (Category 1) H330: Fatal if inhaled. Acute toxicity, (Category 1) H310: Fatal in contact with skin. Skin irritation, (Category 2) H315: Causes skin irritation. Serious eye damage, (Category H318: Causes serious eye damage. 1) Carcinogenicity, (Category 2) H351: Suspected of causing cancer. Reproductive toxicity, (Category H361d: Suspected of damaging the unborn 2) child. Specific target organ toxicity - H336: May cause drowsiness or dizziness. single exposure, (Category 3), Central nervous system Specific target organ toxicity - H372: Causes damage to organs through repeated exposure, (Category 1), prolonged or repeated exposure if Liver, Kidney swallowed. Long-term (chronic) aquatic H411: Toxic to aquatic life with long lasting hazard, (Category 2) effects.