Ethylmagnesium bromide solution

Sigma-Aldrich Chemie GmbH

Revision date : 2022-10-27

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GHS02 GHS05 GHS07
Health risk rating 3
Safety risk rating 5
Environmental risk rating 1

General Information

Revision date

2022-10-27

Product name

Ethylmagnesium bromide solution

REACH No

This

Emergency telephone

0800 181 7059 (CHEMTREC Deutschland

Icons in SDS

GHS07

Company Information

Company name

Sigma-Aldrich Chemie GmbH

E-mail address of the competent person responsible for the Safety Data Sheet

technischerservice@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H224, H260, H302, H314, H318, H336

Hazard statements

Code

Statements

H224

Extremely flammable liquid and vapour

Section 2

CLP CLASSIFICATION

Flammable liquids (Category 1), H224 Substances and mixtures which in contact with water emit flammable gases (Category 1), H260 Acute toxicity, Oral (Category 4), H302 Skin corrosion (Sub-category 1B), H314 Serious eye damage (Category 1), H318 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H336 For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

Labelling according Regulation (EC) No 1272/2008

Signal word

Danger Danger

Hazard statements

H224 Extremely flammable liquid and vapor. H260 In contact with water releases flammable gases which may ignite spontaneously. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H336 May cause drowsiness or dizziness. H224 Extremely flammable liquid and vapor. H314 Causes severe skin burns and eye damage.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P233 Keep container tightly closed. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P403 + P233 Store in a well-ventilated place. Keep container tightly closed.

Supplemental label elements

EUH014 Reacts violently with water. EUH019 May form explosive peroxides. Reduced Labeling (<= 125 ml) EUH014 Reacts violently with water. EUH019 May form explosive peroxides.

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

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